Calculate $$E^{\circ}$$ cell for following.
$$\mathrm{Zn}(s)\left|\mathrm{Zn}^{++}(1 \mathrm{M}) \| \mathrm{Pb}^{++}(1 \mathrm{M})\right| \mathrm{Pb}(s)$$ if $$E_{\mathrm{Zn}}^{\circ}=-0.763 \mathrm{~V}$$ and $$E_{\mathrm{Pb}}^{\circ}=-0.126 \mathrm{~V}$$
Calculate $$\mathrm{E}_{\text {cell }}^0$$ if the equilibrium constant for following reaction is $$1.2 \times 10^6$$.
$$2 \mathrm{Cu}_{(\mathrm{aq})}^{+} \longrightarrow \mathrm{Cu}_{(\mathrm{aq})}^{++}+\mathrm{Cu}_{(\mathrm{s})}$$
Identify the overall oxidation reaction that occurs in lead storage cell during discharge.
Calculate the time required in second to deposit $$6.35 \mathrm{~g}$$ copper from its salt solution by passing 5 ampere current. [Molar mass of $$\mathrm{Cu}=63.5 \mathrm{~g} \mathrm{~mol}^{-1}$$ ]