Arrange the following solutions according to decreasing order of osmotic pressure under similar condition of temperature and assuming complete dissociation.

$$ \begin{array}{|c|l|} \hline \text { I. } & 0.2 \mathrm{~m} \mathrm{KCl} \\ \hline \text { II. } & 0.3 \mathrm{~m} \mathrm{MgSO}_4 \\ \hline \text { III. } & 0.1 \mathrm{~m} \mathrm{BaCl}_2 \\ \hline \text { IV. } & 0.5 \mathrm{~m} \mathrm{Al}_2\left(\mathrm{SO}_4\right)_3 \\ \hline \end{array} $$

Calculate the relative lowering of vapour pressure of solution containing 0.56 g nonvolatile solute in 100 g water [molar mass of solute $=60 \mathrm{~g} \mathrm{~mol}^{-1}$ ]

Which of the following aqueous solutions exhibits lowest freezing point depression assuming complete dissociation?

Calculate the temperature of 0.05 M sucrose solution in Kelvin if the osmotic pressure of the solution is 1.5 atm .

$$ \left[\mathrm{R}=0.0821 \mathrm{dm}^3 \mathrm{~atm} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}\right] $$