MHT CET 2025 23rd April Evening Shift | Electrochemistry Question 10 | Chemistry

A hypothetical galvanic cell is ${ }^{\ominus} \mathrm{A}_{(\mathrm{s})} \mid \stackrel{+}{\mathrm{A}}(1 \mathrm{M})\|\stackrel{+2}{\mathrm{~B}}(1 \mathrm{M})\| \stackrel{\oplus}{\mathrm{B}}_{(\mathrm{s})}$ and emf of cell is positive. What is the possible cell reaction?

$\quad \mathrm{A}_{(\mathrm{s})}+\stackrel{+B}{B}_{(\mathrm{aq})} \longrightarrow \stackrel{+1}{A}_{(\mathrm{aq})}+\mathrm{B}_{(\mathrm{s})}$

$\quad 2 \mathrm{~A}_{(\mathrm{s})}+\stackrel{+}{\mathrm{B}}_{(\mathrm{aq})} \longrightarrow 2 \stackrel{+1}{\mathrm{~A}}_{(\mathrm{aq})}^{+}+\mathrm{B}_{(\mathrm{s})}$

$\quad \mathrm{A}_{(\mathrm{s})}+2 \stackrel{+2 B}{(\mathrm{aq})}^{+2} \xrightarrow{+1} \mathrm{~A}_{(\mathrm{aq})}+2 \mathrm{~B}_{(\mathrm{s})}$

$\quad 2 \stackrel{+}{\mathrm{A}}_{(\mathrm{aq})}+\mathrm{B}_{(\mathrm{s})} \longrightarrow 2 \mathrm{~A}_{(\mathrm{s})}+\stackrel{+2}{\mathrm{~B}}_{(\mathrm{aq})}$

MHT CET 2025 23rd April Morning Shift

MCQ (Single Correct Answer)

-0

Consider galvanic cell, ${ }^{\ominus} \mathrm{A}_{(\mathrm{s})}\left|\mathrm{A}_{(\mathrm{aq})}^{+2}\right|\left|\mathrm{B}_{(\mathrm{aq})}^{+}\right| \mathrm{B}_{(\mathrm{s})}^{\oplus}$

if emf of cell is positive, identify a correct cell reaction from following.

$\quad \mathrm{A}_{(\mathrm{s})}+\mathrm{B}_{(\mathrm{aq})}^{+2} \longrightarrow \mathrm{~A}_{(\mathrm{aq})}^{+2}+\mathrm{B}_{(\mathrm{s})}$

$\quad \mathrm{A}_{(\mathrm{s})}+2 \mathrm{~B}_{(\mathrm{aq})}^{+} \longrightarrow \mathrm{A}_{(\mathrm{aq})}^{+2}+2 \mathrm{~B}_{(\mathrm{s})}$

$\quad 2 \mathrm{~A}_{(\mathrm{aq})}^{+2}+\mathrm{B}_{(\mathrm{s})} \longrightarrow 2 \mathrm{~A}_{(\mathrm{s})}+\mathrm{B}_{(\mathrm{aq})}^{+}$

$\quad 2 \mathrm{~A}_{(\mathrm{s})}+\mathrm{B}_{(\mathrm{aq})}^{+} \longrightarrow 2 \mathrm{~A}_{(\mathrm{aq})}^{+2}+\mathrm{B}_{(\mathrm{s})}$

MHT CET 2025 23rd April Morning Shift

MCQ (Single Correct Answer)

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Standard potential of electrode reaction $\mathrm{Cu}_{(\mathrm{aq})}^{+2}+2 \mathrm{e}^{-} \longrightarrow \mathrm{Cu}_{(\mathrm{s})}$ is +0.34 V .

What is standard potential of reaction

$$ 2 \mathrm{Cu}_{(\mathrm{s})} \longrightarrow 2 \mathrm{Cu}_{(\mathrm{aq})}^{+2}+4 \mathrm{e}^{-} ? $$

+0.68 V

-0.68 V

+0.34 V

-0.34 V

MHT CET 2025 23rd April Morning Shift

MCQ (Single Correct Answer)

-0

What is value of $E_{\text {cell }}$ at 298 K for the reaction, $\mathrm{Zn}_{(\mathrm{s})}+\mathrm{Cu}^{+2}(0.1 \mathrm{M}) \longrightarrow \mathrm{Zn}^{+2}(0.1 \mathrm{M})+\mathrm{Cu}_{(\mathrm{s})}$ if $\mathrm{E}_{\text {cell }}^{\circ}=1.1 \mathrm{~V}$ ?

1.1 V

0.11 V

1.0408 V

0.0296 V

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