18 gram glucose (Molar mass $=180$ ) is dissolved in 100 ml of water at 300 K . If $R=3$ $0.0821 \mathrm{~L}{-\mathrm{a t m}} \mathrm{~mol}^{-1} \mathrm{~K}^{-1}$ what is the osmotic pressure of solution?

Relationship between van't Hoff's factor (i) and degree of dissociation $(\alpha)$ is

9 gram anhydrous oxalic acid (mol. $\mathrm{wt} .=90)$ was dissolved in 9.9 moles of water. If vapour pressure of pure water is $p_1^{\circ}$ the vapour pressure of solution is

Which of the following sets of solutions of urea ( mol . mass $60 \mathrm{~g} \mathrm{~mol}^{-1}$ ) and sucrose ( mol . mass $342 \mathrm{~g} \mathrm{~mol}^{-1}$ ) is isotonic?