The following solutions were prepared by dissolving 10 g of glucose (C₆H₁₂O₆) in 250 ml of water (P₁), 10 g of urea (CH₄N₂O) in 250 ml of water (P₂) and 10 g of sucrose (C₁₂H₂₂O₁₁) in 250 ml of water (P₃). The right option for the decreasing order of osmotic pressure of these solutions is :

The correct option for the value of vapour pressure of a solution at 45$$^\circ$$C with benzene to octane in molar ratio 3 : 2 is :

[At 45$$^\circ$$C vapour pressure of benzene is 280 mm Hg and that of octane is 420 mm Hg. Assume Ideal gas]

The freezing point depression constant (K_r) of benzene is 5. 12 K kg mol^-1. The freezing point depression for the solution of molality 0.078 m containing a non-electrolyte solute in benzene is rounded off upto two decimal places :

The mixture which shows positive deviation from Raoult's law is :