1
AIPMT 2015
MCQ (Single Correct Answer)
+4
-1
Strong reducing behavior of H3PO2 is due to
A
high electron gain enthalpy of phosphorus
B
high oxidation state of phosphorus
C
presence of two $$-$$OH groups and one P$$-$$H bond
D
presence of one $$-$$OH group and two P$$-$$H bonds.
2
AIPMT 2015
MCQ (Single Correct Answer)
+4
-1
The formation of the oxide ion, O2$$-$$(g) from oxygen atom requires first an exthermic and then an endothermic step as shown below:
O(g) + e$$-$$ $$ \to $$ O$$-$$(g);  $$\Delta $$fHo = $$-$$141 kJ mol$$-$$1

O$$-$$(g) + e$$-$$ $$ \to $$ O2$$-$$(g);  $$\Delta $$fHo = +780 kJ mol$$-$$1

Thus, process of formation of O2$$-$$ is isoelectronic with neon. It is due to the fact that,
A
O$$-$$ ion has comparatively smaller size than oxygen atom
B
oxygen is more electronegative
C
addition of electron in oxygen results in larger size of the ion
D
electron repulsion outweighs the stability gained by achieving noble gas configuration.
3
AIPMT 2015
MCQ (Single Correct Answer)
+4
-1
Which of the statements given below is incorrect?
A
O3 molecule is bent.
B
ONF is isoelectronic with O2N
C
OF2 is an oxides of fluorine.
D
Cl2O7 is an anhydride of perchloric acid.
4
AIPMT 2015 Cancelled Paper
MCQ (Single Correct Answer)
+4
-1
Nitrogen dioxide and sulphur dioxide have some properties in common . Which property is shown by one of these compounds , but not by the other?
A
Is soluble in water.
B
Is used as a food preservative.
C
Forms 'acid-rain'.
D
Is a reducing agent.
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