1
NEET 2022 Phase 2
MCQ (Single Correct Answer)
+4
-1

Match List-I with List-II :

List-I
(Complexes)
List-II
(Types)
(a) $$[Co{(N{H_3})_5}N{O_2}]C{l_2}$$ and $$[Co{(N{H_3})_5}ONO]C{l_2}$$ (i) ionisation isomerism
(b) $$[Cr{(N{H_3})_6}][Co{(CN)_6}]$$ and $$[Cr{(CN)_6}][Co{(N{H_3})_6}]$$ (ii) coordination isomerism
(c) $$[Co{(N{H_3})_5}(S{O_4})]Br$$ and $$[Co{(N{H_3})_5}Br]S{O_4}$$ (iii) linkage isomerism
(d) $$[Cr{({H_2}O)_6}]C{l_3}$$ and $$[Cr{({H_2}O)_5}Cl]C{l_2}\,.\,{H_2}O$$ (iv) solvate isomerism

Choose the correct answer from the options given below :

A
(a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)
B
(a)-(iii), (b)-(i), (c)-(ii), (d)-(iv)
C
(a)-(ii), (b)-(iii), (c)-(iv), (d)-(i)
D
(a)-(iii), (b)-(ii), (c)-(i), (d)-(iv)
2
NEET 2022 Phase 2
MCQ (Single Correct Answer)
+4
-1

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : The metal carbon bond in metal carbonyls possesses both $$\sigma$$ and $$\pi$$ character.

Reason (R) : The ligand to metal bond is a $$\pi$$ bond and metal to ligand bond is a $$\sigma$$ bond.

In the light of the above statements, choose the most appropriate answer from the options given below.

A
(A) is not correct but (R) is correct
B
Both (A) and (R) are correct and (R) is the correct explanation of (A)
C
Both (A) and (R) are correct but (R) is not the correct explanation of (A)
D
(A) is correct but (R) is not correct
3
NEET 2022 Phase 1
MCQ (Single Correct Answer)
+4
-1

The IUPAC name of the complex -

[Ag(H2O)2][Ag(CN)2] is:

A
dicyanidosilver(II) diaquaargentate (II)
B
diaquasilver(II) dicyanidoargentate(II)
C
dicyanidosilver(I) diaquaargentate(I)
D
diaquasilver(I) dicyanidoargentate(I)
4
NEET 2022 Phase 1
MCQ (Single Correct Answer)
+4
-1

The order of energy absorbed which is responsible for the color of complexes

(A) [Ni(H2O)2(en)2]2+

(B) [Ni(H2O)4(en)]2+ and

(C) [Ni(en)3]2+

is

A
(A) > (B) > (C)
B
(C) > (B) > (A)
C
(C) > (A) > (B)
D
(B) > (A) > (C)
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