Which from following transformations is endothermic in nature?

Calculate the standard enthalpy change for synthesis of ammonia gas from following data.

i. $\quad 2 \mathrm{H}_{2(\mathrm{~g})}+\mathrm{N}_{2(\mathrm{~g})} \longrightarrow \mathrm{N}_2 \mathrm{H}_{4(\mathrm{~g})} ; \Delta_{\mathrm{r}} \mathrm{H}_1^0=95.4 \mathrm{~kJ}$

ii. $\quad \mathrm{N}_2 \mathrm{H}_{4(\mathrm{~g})}+\mathrm{H}_{2(\mathrm{~g})} \longrightarrow 2 \mathrm{NH}_{3(\mathrm{~g})}$;$$ \Delta_{\mathrm{t}} \mathrm{H}_2^0=-187.6 \mathrm{~kJ} $$

Identify from following the correct set of thermodynamic conditions for the reaction to be spontaneous below equilibrium temperature.

Calculate work done if 1 mole of an ideal gas expands isothermally from $2 \mathrm{dm}^3$ to $2.8 \mathrm{dm}^3$ against constant external pressure 1 atm .