In a particular reaction ' x ' kJ of heat is released by the system and ' y ' kJ of work done is done on the system. What is internal energy change?

Calculate the value of $\Delta G$ for the following reaction. $\mathrm{N}_2 \mathrm{O}_{4(\mathrm{~g})} \longrightarrow 2 \mathrm{NO}_{2(\mathrm{~g})}$ if $\Delta \mathrm{H}=57.44 \mathrm{~kJ}$ and $\Delta \mathrm{S}=176 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$.

Under similar conditions enthalpy of freezing is exactly opposite to

100 ml of $\mathrm{H}_{2(\mathrm{~g})}$ and 100 ml of $\mathrm{Cl}_{2(\mathrm{~g})}$ were allowed to react at 1 bar pressure as

$$\mathrm{H}_{2(\mathrm{~g})}+\mathrm{Cl}_{2(\mathrm{~g})} \longrightarrow 2 \mathrm{HCl}_{(\mathrm{g})}$$

What will be the PV type of work done during reaction?