Identify from following the correct set of thermodynamic conditions for the reaction to be spontaneous below equilibrium temperature.

Calculate work done if 1 mole of an ideal gas expands isothermally from $2 \mathrm{dm}^3$ to $2.8 \mathrm{dm}^3$ against constant external pressure 1 atm .

Which from following reactions is exothermic?

Calculate work done in isothermal reversible expansion of 1 mole ideal gas from initial pressure 10 bar to final pressure 1 bar at 300 K . $\left(\mathrm{R}=8.314 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}\right)$.