Calculate the standard enthalpy change of following reaction.

$$ \mathrm{C}_2 \mathrm{H}_{4(\mathrm{~g})}+3 \mathrm{O}_{2(\mathrm{~g})} \longrightarrow 2 \mathrm{CO}_{2(\mathrm{~g})}+2 \mathrm{H}_2 \mathrm{O}_{(l)} $$

If $\Delta_{\mathrm{f}} \mathrm{H}^{\circ}\left(\mathrm{C}_2 \mathrm{H}_4\right)=-52 \mathrm{~kJ} \mathrm{~mol}^{-1}$

$$ \begin{aligned} & \Delta_{\mathrm{f}} \mathrm{H}^{\circ}\left(\mathrm{CO}_2\right)=-390 \mathrm{~kJ} \mathrm{~mol}^{-1} \\ & \Delta_{\mathrm{f}} \mathrm{H}^{\circ}\left(\mathrm{H}_2 \mathrm{O}\right)=-286 \mathrm{~kJ} \mathrm{~mol}^{-1} \end{aligned} $$

Which from following process involves zero work done?

Calculate the constant external pressure required to expand 2 moles of an ideal gas from volume $15 \mathrm{dm}^3$ to $20 \mathrm{dm}^3$ if amount of work done is -600 J .

Calculate the enthalpy of vaporisation of ethanol if 11.5 g of ethanol is completely vaporised by supplying 11.8 kJ of heat.