Calculate the standard enthalpy change of following reaction.
$$ \begin{aligned} & \mathrm{CH}_{4(\mathrm{~s})}+2 \mathrm{O}_{2(\mathrm{~g})} \rightarrow \mathrm{CO}_{2(\mathrm{~g})}+2 \mathrm{H}_2 \mathrm{O}_{(\ell)} \\ & \text { if } \Delta_{\mathrm{f}} \mathrm{H}^{-}\left(\mathrm{CH}_4\right)=-75 \mathrm{~kJ} \mathrm{~mol}^{-1} \end{aligned} $$
$$ \Delta_{\mathrm{f}} \mathrm{H}^*\left(\mathrm{CO}_2\right)=-390 \mathrm{~kJ} \mathrm{~mol}^{-1} $$
$$ \Delta_{\mathrm{r}} \mathrm{H}^{\circ}\left(\mathrm{H}_2 \mathrm{O}\right)=-286 \mathrm{~kJ} \mathrm{~mol}^{-1} $$
Calculate the change in internal energy of the system if work done by the system is 18 joule and absorbs heat 50 joule in a particular reaction.
Identify from following the correct set of thermodynamic conditions for a reaction to be nonspontaneous at all temperatures.