1
AIPMT 2004
MCQ (Single Correct Answer)
+4
-1
Standard enthalpy and standard entropy changes for the oxidation of ammonia at 298 K are $$-$$ 382.64 kJ mol$$-$$1 and $$-$$ 145.6 kJ mol$$-$$1, respectively. Standard Gibb's energy change for the same reaction at 298 K is
A
$$-$$ 221.1 kJ mol$$-$$1
B
$$-$$339.3 kJ mol$$-$$1
C
$$-$$ 439.3 kJ mol$$-$$1
D
$$-$$ 523.2 kJ mol$$-$$1
2
AIPMT 2004
MCQ (Single Correct Answer)
+4
-1
If the bond energies of H $$-$$ H, Br $$-$$ Br, and H $$-$$ Br are 433, 192 and 364 kJ mol$$-$$1 respectively, the $$\Delta $$Ho for the reaction

H2(g) + Br2(g) $$ \to $$ 2HBr(g) is
A
$$-$$ 261 kJ
B
+103 kJ
C
+261 kJ
D
$$-$$103 kJ
3
AIPMT 2004
MCQ (Single Correct Answer)
+4
-1
Considering entropy (S) as a thermodynamic parameter, the criterion for the spontaneity of any process is
A
$$\Delta {S_{system}} + \Delta {S_{surroundings}} > 0$$
B
$$\Delta {S_{system}} - \Delta {S_{surroundings}} > 0$$
C
$$\Delta {S_{system}} > 0\,\,\,$$only
D
$$\Delta {S_{surroundings}} > 0$$ only
4
AIPMT 2003
MCQ (Single Correct Answer)
+4
-1
For the reaction,
C3H8(g) + 5O2(g) $$ \to $$ 3CO2(g) + 4H2O(l)
at constant temperature, $$\Delta $$H $$-$$ $$\Delta $$E is
A
+ RT
B
$$-$$3RT
C
+ 3RT
D
$$-$$ RT
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