1
AIPMT 2008
MCQ (Single Correct Answer)
+4
-1
For the gas phase reaction,

PCl5(g)  $$\rightleftharpoons$$ PCl3(g) + Cl2(g)

which of the following conditions are correct ?
A
$$\Delta $$H < 0 and $$\Delta $$S < 0
B
$$\Delta $$H > 0 and $$\Delta $$S < 0
C
$$\Delta $$H = 0 and $$\Delta $$S < 0
D
$$\Delta $$H > 0 and $$\Delta $$S > 0
2
AIPMT 2007
MCQ (Single Correct Answer)
+4
-1
Consider the following reactions :
(i) H+(aq) + OH$$-$$(aq) = H2O(l),  $$\Delta $$H = $$-$$ X1 kJ mol$$-$$1
(ii) H2(g) + 1/2O2(g) = H2O(l),   $$\Delta $$H = $$-$$ X2 kJ mol$$-$$1
(iii) CO2(g) + H2(g) = CO(g) + H2O(l),  $$\Delta $$H = $$-$$ X3 kJ mol$$-$$1
(iv) C2H2(g) + 5/2O2(g) = 2CO2(g) + H2O(l),    $$\Delta $$H = +X4 kJ mol$$-$$1

Enthalpy of formation of H2O(l) is
A
+X3 kJ mol$$-$$1
B
$$-$$X4 kJ mol$$-$$1
C
+X1 kJ mol$$-$$1
D
$$-$$X2 kJ mol$$-$$1
3
AIPMT 2007
MCQ (Single Correct Answer)
+4
-1
Given that bond energies of H $$-$$ H and Cl $$-$$ Cl are 430 kJ mol$$-$$1 and 240 kJ mol$$-$$1 respectively and $$\Delta $$Hf for HCl is $$-$$ 90 kJ mol$$-$$1, bond enthalpy of HCl is
A
380 kJ mol$$-$$1
B
425 kJ mol$$-$$1
C
245 kJ mol$$-$$1
D
290 kJ mol$$-$$1
4
AIPMT 2006
MCQ (Single Correct Answer)
+4
-1
Identify the correct statement for change of Gibb's energy for a system ($$\Delta $$Gsystem) at constant temperature and pressure.
A
If $$\Delta $$Gsystem < 0, the process is not spontaneous.
B
If $$\Delta $$Gsystem > 0, the process is spontaneous.
C
If $$\Delta $$Gsystem = 0, the system has attained equilibrium.
D
If $$\Delta $$Gsystem = 0, the system is till moving in a particular direction.
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