1
COMEDK 2024 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Which of the following 2 compounds exhibit both Geometrical and Structural isomerism?

$$\begin{aligned} & \mathrm{A}=\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right] \mathrm{NO}_2 \\ & \mathrm{~B}=\left[\mathrm{Co}\left(\mathrm{NH}_3\right) \mathrm{Br}\right] \mathrm{SO}_4 \\ & \mathrm{C}=\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3\left(\mathrm{NO}_2\right)_3\right] \\ & \mathrm{D}=\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right] \mathrm{Cl}_3 \end{aligned}$$

A
A & C
B
C & B
C
B & D
D
A & B
2
COMEDK 2024 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Based on Valence Bond Theory, match the complexes listed in Column I with the number of unpaired electrons on the central metal ion, given in Column II

No. Complex ions No. Number of unpaired electrons
(A) $$
\left[\mathrm{Fe} \mathrm{F}_6\right]^{3-}
$$
(P) 0
(B) $$
\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-}
$$
(P) 1
(C) $$
\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}
$$
(R) 5
(D) $$
\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{3-}
$$
(S) 4

A
$$ \mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{Q} \quad \mathrm{C}=\mathrm{R} \quad \mathrm{D}=\mathrm{P} $$
B
$$ \mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{Q} \quad \mathrm{C}=\mathrm{P} \quad \mathrm{D}=\mathrm{R} $$
C
$$ \mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{P} \quad \mathrm{C}=\mathrm{S} \quad \mathrm{D}=\mathrm{Q} $$
D
$$ \mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{S} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{P} $$
3
COMEDK 2024 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Given below are 4 statements. Two of these are correct statements. Identify them.

A. $$\mathrm{Co}^{2+}$$ is easily oxidised to $$\mathrm{Co}^{3+}$$ in the presence of a strong ligand like $$\mathrm{CN}^{-}$$

B. $$[\mathrm{Fe}(\mathrm{CN})_6]^{4-}$$ is an octahedral complex ion which is paramagnetic in nature.

C. Removal of $$\mathrm{H}_2 \mathrm{O}$$ molecules from $$[\mathrm{Ti}(\mathrm{H}_2 \mathrm{O})_6] \mathrm{Cl}_3$$ on strong heating converts it to a colourless compound.

D. Crystal Field splitting in Octahedral and Tetrahedral complexes is given by the equation $$\Delta_0=4 / 9 \Delta_t$$

A
A & C
B
A & D
C
B & D
D
C & B
4
COMEDK 2024 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Based on Crystal Field theory, match the Complex ions listed in Column I with the electronic configuration in the d orbitals of the central metal ion listed in Column II.

No. Complexion No. d orbital configuration of central metal ion.
(A) $$
\left[M n(C N)_6\right]^{4-}
$$
(P) $$
e_g^2 t_{2 g}^3
$$
(B) $$
\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}
$$
(Q) $$
t_{2 g}^4 e_g^2
$$
(C) $$
\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}
$$
(R) $$
t_{2 g}^5
$$
(D) $$
\left[\mathrm{MnCl}_4\right]^{2-}
$$
(S) $$
t_{2 g}^5 e_g^2
$$

A
$$ \mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{R} \quad \mathrm{C}=\mathrm{P} \quad \mathrm{D}=\mathrm{Q} $$
B
$$ \mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{S} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{P} $$
C
$$ \mathrm{A}=\mathrm{Q} \quad \mathrm{B}=\mathrm{S} \quad \mathrm{C}=\mathrm{P} \quad \mathrm{D}=\mathrm{R} $$
D
$$ \mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{S} \quad \mathrm{C}=\mathrm{P} \quad \mathrm{D}=\mathrm{Q} $$
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