Practical Organic Chemistry · Chemistry · COMEDK

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MCQ (Single Correct Answer)

1

$$ \text { Match the mixtures listed in Column I with the correct method used for their separation. } $$

$$
\text { Column I }
$$
$$
\text { Column I }
$$
A Glycerol from spent Lye P Steam distillation
B Mixture of Benzoic acid and Naphthalene dissolved in organic solvent Q Distillation
C Aniline & Chloroform R Distillation under reduced pressure
D 2- Nitrophenol & 4- Nitrophenol S Differential extraction using $\mathrm{NaHCO}_3$
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2

Lassaigne's test for the detection of nitrogen fails in

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3
The best method for the separation of $o$-nitrophenol and $p$-nitrophenol from their mixture is :
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4

In the estimation of element $$\mathrm{X}$$ in an organic compound, $$0.8 \mathrm{~g}$$ of the compound containing $$\mathrm{X}$$ was heated with fuming $$\mathrm{HNO}_3$$ and the cooled product was treated with barium chloride. The mass of barium sulphate precipitated was $$1.2 \mathrm{~g}$$. What is the percentage of element $$\mathrm{X}$$ and what is the formula of the violet-coloured compound formed when Lassaigne's extract of the organic compound is treated with sodium nitroprusside?

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5

Presence of halogen in organic compounds can be detected using

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