1
COMEDK 2024 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0

On the basis of crystal field theory, electronic configuration of a low spin $$\mathrm{d}^4$$ complex is:

A
$$t_{2 g}^1 e_g^3$$
B
$$t_{2 g}^4 e_g$$
C
$$t_{2 g}^3 e_g^1$$
D
$$t_{2 g}^2 e_g^2$$
2
COMEDK 2024 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0

The molar conductivity of the complex $$\mathrm{CoCl}_3 \cdot 4 \mathrm{NH}_3 \cdot 2 \mathrm{H}_2 \mathrm{O}$$ is found to be the same as that of a $$1: 3$$ electrolyte. The structural formula of the compound is :

A
$$ \left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4\left(\mathrm{H}_2 \mathrm{O}\right)_2\right] \mathrm{Cl}_3 $$
B
$$ \left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}\left(\mathrm{H}_2 \mathrm{O}\right)\right] \mathrm{Cl}_2 \mathrm{H}_2 \mathrm{O} $$
C
$$ \left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4\left(\mathrm{H}_2 \mathrm{O}\right) \mathrm{Cl}_2\right] \mathrm{Cl} \mathrm{H}_2 \mathrm{O} $$
D
$$ \left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4\left(\mathrm{H}_2 \mathrm{O}\right)_2 \mathrm{Cl}\right] \mathrm{Cl}_2 $$
3
COMEDK 2024 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0

The type of hybridisation and the spin only magnetic moment for the complex $$[\mathrm{Ni}(\mathrm{CO})_4]$$ are respectively:

A
$$\mathrm{sp}^3, \sqrt{8} \mathrm{~BM}$$
B
$$\mathrm{dsp}^2$$, zero
C
$$\mathrm{sp}^3$$, zero
D
$$\mathrm{dsp}^2, \sqrt{8} \mathrm{~BM}$$
4
COMEDK 2024 Morning Shift
MCQ (Single Correct Answer)
+1
-0

A d - block metal $$\mathrm{X}(\mathrm{Z}=26)$$ forms a compound $$[\mathrm{X}(\mathrm{CN})_2(\mathrm{CO})_4]^{+}$$. Calculate its spin magnetic moment value.

A
2.83 BM
B
1.73 BM
C
3.87 BM
D
5.92 BM
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