Liquid Solution · Chemistry · COMEDK

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MCQ (Single Correct Answer)

1

Study the graph between partial pressure and mole fraction of some gases and arrange the gases P, Q, R and S dissolved in H$$_2$$O, in the decreasing order of their KH values.

COMEDK 2024 Evening Shift Chemistry - Liquid Solution Question 1 English

COMEDK 2024 Evening Shift
2

Given that the freezing point of benzene is $$5.48^{\circ} \mathrm{C}$$ and its $$\mathrm{K}_{\mathrm{f}}$$ value is $$5.12{ }^{\circ} \mathrm{C} / \mathrm{m}$$. What would be the freezing point of a solution of $$20 \mathrm{~g}$$ of propane in $$400 \mathrm{~g}$$ of benzene?

COMEDK 2024 Evening Shift
3

A solute $$\mathrm{X}$$ is found to exist as a dimer in water. A 4 molal solution of $$\mathrm{X}$$ shows a boiling point of $$101.04^{\circ} \mathrm{C}$$. What is the percentage association of $$\mathrm{X}$$ ? ($$\mathrm{K}_{\mathrm{b}}$$ for water $$=0.52 \mathrm{~K} / \mathrm{m}$$).

COMEDK 2024 Evening Shift
4

$$200 \mathrm{ml}$$ of an aqueous solution contains $$3.6 \mathrm{~g}$$ of Glucose and $$1.2 \mathrm{~g}$$ of Urea maintained at a temperature equal to $$27^{\circ} \mathrm{C}$$. What is the Osmotic pressure of the solution in atmosphere units?

$$\mathrm{R}=0.082 \mathrm{~L} \mathrm{~atm} \mathrm{~K}{ }^{-1} \mathrm{~mol}^{-1}$$ : Molecular Formula: Glucose is $$\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6$$ and of Urea is $$\mathrm{NH}_2 \mathrm{CONH}_2$$

COMEDK 2024 Evening Shift
5

$$\mathrm{K}_{\mathrm{H}}$$ for $$\mathrm{O}_2$$ at $$293 \mathrm{~K}$$ is $$34.86 \mathrm{~kbar}$$. What should be the partial pressure of $$\mathrm{O}_2$$ gas so that it has a solubility of $$0.08 \mathrm{~g} / \mathrm{L}$$ in water at $$293 \mathrm{~K}$$ ? (Density of solution $$=1 \mathrm{~g} / \mathrm{ml}$$)

COMEDK 2024 Morning Shift
6

What is the amount of ice that separates out on cooling a solution containing $$60 \mathrm{~g}$$ of Ethylene glycol in $$250 \mathrm{~g}$$ of water to $$-9.3^{\circ} \mathrm{C}$$ ? $$\mathrm{K}_{\mathrm{f}}$$ of $$\mathrm{H}_2 \mathrm{O}=1.86 \mathrm{~K} / \mathrm{m} ;$$ MM of ethylene glycol= $$62 \mathrm{~amu}$$

COMEDK 2024 Morning Shift
7

$$\text { If a compound } \mathrm{X}_3 \mathrm{Y} \text { is } 60 \% \text { ionised in aqueous medium, what is its van't Hoff factor value? }$$

COMEDK 2024 Morning Shift
8

COMEDK 2024 Morning Shift Chemistry - Liquid Solution Question 5 English

Above figure represents Vapour pressure versus Temperature graphs of 2 pure volatile liquids and a solution formed by the 2 liquids.

(i) Which curve represents the solution?

(ii) Which curve represents the liquid with the strongest intermolecular forces of attraction?

COMEDK 2024 Morning Shift
9

The boiling point of a $$4 \%$$ aqueous solution of a non-volatile solute $$\mathrm{P}$$ is equal to the boiling point of $$\mathrm{X} \%$$ solution of another non-volatile solute $$\mathrm{Q}$$. The relation between their Molar masses is $$\mathrm{M}_{\mathrm{Q}}=4 \mathrm{~Mp}$$. What is $$\mathrm{X}$$ ?

COMEDK 2024 Morning Shift
10

Which of the following is incorrect regarding Henry's law?

COMEDK 2023 Morning Shift
11

Which of the following shows negative deviation from Raoult's law?

COMEDK 2023 Morning Shift
12

$$5 \mathrm{~g}$$ of non-volatile water soluble compound $$X$$ is dissolved in $$100 \mathrm{~g}$$ of water. The elevation in boiling point is found to be 0.25. The molecular mass of compound $$X$$ is

COMEDK 2023 Morning Shift
13

Abnormal colligative properties are observed only when the dissolved non-volatile solute in a given dilute solution

COMEDK 2023 Morning Shift
14

What would be the van't Hoff factor for a solution prepared by dissolving $$3.42 \mathrm{~g}$$ of $$\mathrm{CaCl}_2$$ in $$2500 \mathrm{~ml}$$ of water having an Osmotic pressure equal to $$0.75 \mathrm{~atm}$$. at $$27^{\circ} \mathrm{C}$$ ? Molar mass of $$\mathrm{CaCl}_2=111 \mathrm{~amu}$$.

COMEDK 2023 Evening Shift
15

What is the mole fraction of solute in a $$5 \mathrm{~m}$$ aqueous solution?

COMEDK 2023 Evening Shift
16

Choose the incorrect statement:

COMEDK 2023 Evening Shift
17

$$\mathrm{X}$$ is an electrolyte with a concentration of $$0.04 \mathrm{M}$$ whose formula is of the type $$\mathrm{X}_2 \mathrm{~A}$$. $$\mathrm{Y}$$ is a non-electrolyte solution with a concentration of $$0.2 \mathrm{M}$$ and has an osmotic pressure equal to $$\mathrm{P}_2$$ at room temperature. What is the relationship between the Osmotic pressure $$\pi$$ of $$\mathrm{X}$$ and $$\mathrm{P}_2$$ ?

COMEDK 2023 Evening Shift
18

If the depression in freezing point of an aqueous solution containing a solute, which is neither dissociated nor associated, is $$\mathbf{a} \mathrm{K}$$ with $$\mathrm{K}_{\mathrm{f}}=\mathbf{b ~ K ~ k g ~ m o l}{ }^{-1}$$, what would be the elevation in boiling point $$(\mathrm{X})$$ for this solution if its $$\mathrm{K}_{\mathrm{b}}=\mathbf{\mathrm { ~K } \mathrm { ~K } \mathrm { ~kg } \mathrm { ~mol }}{ }^{-1}$$ ?

COMEDK 2023 Evening Shift
19

The system that forms maximum boiling azeotropes is

COMEDK 2022
20

Which of the following does not affect solubility of a gas in liquid?

COMEDK 2022
21

Which among the following forms minimum boiling azeotropes?

(i) Heptane + Octane

(ii) Water + Nitric acid

(iii) Ethanol + Water

(iv) Acetone + Carbon dioxide

COMEDK 2022
22

The solution which have lowest freezing point is

COMEDK 2022
23

Under which of the following condition, the gases does not follow Henry's law?

COMEDK 2021
24

Which of the following is correct mixture of azeotrope?

COMEDK 2021
25

Which of the following is correct order of their increasing boiling points?

COMEDK 2021
26

When KBr is dissolved in water, K$$^+$$ ions are

COMEDK 2020
27

The volume of 10N and 4N HCl required to make 1 litre of 7N HCl are

COMEDK 2020
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