Liquid Solution · Chemistry · COMEDK
MCQ (Single Correct Answer)
Study the graph between partial pressure and mole fraction of some gases and arrange the gases P, Q, R and S dissolved in H$$_2$$O, in the decreasing order of their KH values.
Given that the freezing point of benzene is $$5.48^{\circ} \mathrm{C}$$ and its $$\mathrm{K}_{\mathrm{f}}$$ value is $$5.12{ }^{\circ} \mathrm{C} / \mathrm{m}$$. What would be the freezing point of a solution of $$20 \mathrm{~g}$$ of propane in $$400 \mathrm{~g}$$ of benzene?
A solute $$\mathrm{X}$$ is found to exist as a dimer in water. A 4 molal solution of $$\mathrm{X}$$ shows a boiling point of $$101.04^{\circ} \mathrm{C}$$. What is the percentage association of $$\mathrm{X}$$ ? ($$\mathrm{K}_{\mathrm{b}}$$ for water $$=0.52 \mathrm{~K} / \mathrm{m}$$).
$$200 \mathrm{ml}$$ of an aqueous solution contains $$3.6 \mathrm{~g}$$ of Glucose and $$1.2 \mathrm{~g}$$ of Urea maintained at a temperature equal to $$27^{\circ} \mathrm{C}$$. What is the Osmotic pressure of the solution in atmosphere units?
$$\mathrm{R}=0.082 \mathrm{~L} \mathrm{~atm} \mathrm{~K}{ }^{-1} \mathrm{~mol}^{-1}$$ : Molecular Formula: Glucose is $$\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6$$ and of Urea is $$\mathrm{NH}_2 \mathrm{CONH}_2$$
An aqueous solution of glucose boils at $$100.01^{\circ} \mathrm{C}$$. The number of glucose molecules in a solution containing $$100 \mathrm{~g}$$ of water is _________ [$$\mathrm{K}_{\mathrm{b}}$$ for water is $$0.5 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$$]
The system that forms minimum boiling azeotrope is :
A solution of $$\mathrm{KCl}(\mathrm{M}=74.5 \mathrm{~g} \mathrm{~mol}^{-1})$$ containing $$1.9 \mathrm{~g}$$ per $$100 \mathrm{~mL}$$ of $$\mathrm{KCl}$$ is isotonic with a solution of urea $$(\mathrm{M}=60.0 \mathrm{~g} \mathrm{~mol}^{-1}$$) containing $$3 \mathrm{~g}$$ per $$100 \mathrm{~mL}$$ of urea. The degree of dissociation of $$\mathrm{KCl}$$ is: [Assume both the solutions are kept at same temperature]
Which among the following compounds has the highest freezing point of its 1 molal aqueous solution?
In the following question a statement of Assertion (A) followed by a statement of Reason (R) is given. Choose the correct option out of the choices given below.
Assertion (A): van't Hoff factor for a solution of benzoic acid in benzene is less than one.
Reason(R): Benzoic acid undergoes dissociation in benzene and its calculated molecular mass using colligative properties is lower than its actual molecular mass.
$$\mathrm{K}_{\mathrm{H}}$$ for $$\mathrm{O}_2$$ at $$293 \mathrm{~K}$$ is $$34.86 \mathrm{~kbar}$$. What should be the partial pressure of $$\mathrm{O}_2$$ gas so that it has a solubility of $$0.08 \mathrm{~g} / \mathrm{L}$$ in water at $$293 \mathrm{~K}$$ ? (Density of solution $$=1 \mathrm{~g} / \mathrm{ml}$$)
What is the amount of ice that separates out on cooling a solution containing $$60 \mathrm{~g}$$ of Ethylene glycol in $$250 \mathrm{~g}$$ of water to $$-9.3^{\circ} \mathrm{C}$$ ? $$\mathrm{K}_{\mathrm{f}}$$ of $$\mathrm{H}_2 \mathrm{O}=1.86 \mathrm{~K} / \mathrm{m} ;$$ MM of ethylene glycol= $$62 \mathrm{~amu}$$
$$\text { If a compound } \mathrm{X}_3 \mathrm{Y} \text { is } 60 \% \text { ionised in aqueous medium, what is its van't Hoff factor value? }$$
Above figure represents Vapour pressure versus Temperature graphs of 2 pure volatile liquids and a solution formed by the 2 liquids.
(i) Which curve represents the solution?
(ii) Which curve represents the liquid with the strongest intermolecular forces of attraction?
The boiling point of a $$4 \%$$ aqueous solution of a non-volatile solute $$\mathrm{P}$$ is equal to the boiling point of $$\mathrm{X} \%$$ solution of another non-volatile solute $$\mathrm{Q}$$. The relation between their Molar masses is $$\mathrm{M}_{\mathrm{Q}}=4 \mathrm{~Mp}$$. What is $$\mathrm{X}$$ ?
Which of the following is incorrect regarding Henry's law?
Which of the following shows negative deviation from Raoult's law?
$$5 \mathrm{~g}$$ of non-volatile water soluble compound $$X$$ is dissolved in $$100 \mathrm{~g}$$ of water. The elevation in boiling point is found to be 0.25. The molecular mass of compound $$X$$ is
Abnormal colligative properties are observed only when the dissolved non-volatile solute in a given dilute solution
What would be the van't Hoff factor for a solution prepared by dissolving $$3.42 \mathrm{~g}$$ of $$\mathrm{CaCl}_2$$ in $$2500 \mathrm{~ml}$$ of water having an Osmotic pressure equal to $$0.75 \mathrm{~atm}$$. at $$27^{\circ} \mathrm{C}$$ ? Molar mass of $$\mathrm{CaCl}_2=111 \mathrm{~amu}$$.
What is the mole fraction of solute in a $$5 \mathrm{~m}$$ aqueous solution?
Choose the incorrect statement:
$$\mathrm{X}$$ is an electrolyte with a concentration of $$0.04 \mathrm{M}$$ whose formula is of the type $$\mathrm{X}_2 \mathrm{~A}$$. $$\mathrm{Y}$$ is a non-electrolyte solution with a concentration of $$0.2 \mathrm{M}$$ and has an osmotic pressure equal to $$\mathrm{P}_2$$ at room temperature. What is the relationship between the Osmotic pressure $$\pi$$ of $$\mathrm{X}$$ and $$\mathrm{P}_2$$ ?
If the depression in freezing point of an aqueous solution containing a solute, which is neither dissociated nor associated, is $$\mathbf{a} \mathrm{K}$$ with $$\mathrm{K}_{\mathrm{f}}=\mathbf{b ~ K ~ k g ~ m o l}{ }^{-1}$$, what would be the elevation in boiling point $$(\mathrm{X})$$ for this solution if its $$\mathrm{K}_{\mathrm{b}}=\mathbf{\mathrm { ~K } \mathrm { ~K } \mathrm { ~kg } \mathrm { ~mol }}{ }^{-1}$$ ?
The system that forms maximum boiling azeotropes is
Which of the following does not affect solubility of a gas in liquid?
Which among the following forms minimum boiling azeotropes?
(i) Heptane + Octane
(ii) Water + Nitric acid
(iii) Ethanol + Water
(iv) Acetone + Carbon dioxide
The solution which have lowest freezing point is
Under which of the following condition, the gases does not follow Henry's law?
Which of the following is correct mixture of azeotrope?
Which of the following is correct order of their increasing boiling points?
When KBr is dissolved in water, K$$^+$$ ions are
The volume of 10N and 4N HCl required to make 1 litre of 7N HCl are