1
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Which of the coordination compounds [(i) to (v)] are used for the following processes :

A: Electroplating

B: Removal of excess copper from human body

C: Estimation of hardness of water

(i) DMG (ii) $\mathrm{Na}_2 \mathrm{EDTA}$ (iii) Cis-platin (iv) D-penicillamine (v) $\mathrm{K}\left[\mathrm{Au}(\mathrm{CN})_2\right]$

A
$\mathrm{A}=\mathrm{iv} \quad \mathrm{B}=\mathrm{i} \quad \mathrm{C}=\mathrm{iii}$
B
$A=i \quad B=i i i \quad C=i v$
C
$\mathrm{A}=\mathrm{v} \quad \mathrm{B}=\mathrm{iv} \quad \mathrm{C}=\mathrm{ii}$
D
$A=$ iii $\quad B=$ ii $\quad C=i$
2
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0

Which one of the following structures in Column I does not have the correct IUPAC name as given in Column II.

S.No. Structure IUPAC name
A. $\left[\mathrm{CoBr}_2(\mathrm{en})_2\right] \mathrm{Cl}$ P. Dibromidodi-( ethan-1, 2 - diamine)cobalt (III) chloride
B. $\mathrm{Na}\left[\mathrm{PtBrCl}\left(\mathrm{NO}_2\right)\left(\mathrm{NH}_3\right)\right]$ Q. Sodium amminebromidochloridonitrito- N - palatinate(II)
C. $\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_2\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}\right] \mathrm{SO}_4$ R. Tetraamminediaquachloridochromium (III) sulphate.
D. $\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_4\right]\left[\mathrm{PtCl}_4\right]$ S. Tetraammineplatinum (II) tetrachloridoplatinate (II)

A
B
B
A
C
D
D
C
3
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0
A transition metal M forms 4 homoleptic octahedral coordination compounds, $\mathrm{A}, \mathrm{B}, \mathrm{C}$ and D of the type $\left[\mathrm{MX}_6\right]^{z-}$ with monodentate ligands a, b, c and d respectively. These compounds absorb red. blue. yellow and blue-green light respectively. Which one of the options shows the correct order of decreasing ligand strength?
A
$\mathrm{B}>\mathrm{D}>\mathrm{C}>\mathrm{A}$
B
$\mathrm{D}>\mathrm{C}>\mathrm{B}>\mathrm{A}$
C
$\mathrm{A}>\mathrm{C}>\mathrm{D}>\mathrm{B}$
D
$\mathrm{A}>\mathrm{B}>\mathrm{C}>\mathrm{D}$
4
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0
Choose the coordination compound which does not exhibit Optical activity.
A
cis $-\left[\mathrm{PtCl}_2(\mathrm{en}) 2\right]^{2+}$
B
$\left[\mathrm{Co}(\mathrm{en})_3\right]^{3+}$
C
trans $-\left[\mathrm{CoCl}_2(\mathrm{en})_2\right]^{+}$
D
cis $-\left[\mathrm{CoCl}_2(\mathrm{en})_2\right]^{+}$
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