What would be the EMF of the cell in which the following reaction occurs:
$$\begin{aligned} & \mathrm{Cd}(\mathrm{S})+2 \mathrm{H}^{+} \rightarrow \mathrm{Cd}^{2+}+\mathrm{H}_{2(\mathrm{~g})} \\ & {\left[\mathrm{H}^{+}\right]=0.02 \mathrm{M} \quad \mathrm{E}^0\left(\mathrm{Cd}^{2+} / \mathrm{Cd}\right)=-0.4 \mathrm{~V},\left[\mathrm{Cd}^{2+}\right]=0.01 \mathrm{M} \text { and partial pressure of } \mathrm{H}_2 \text { gas }=0.8 \mathrm{~atm} .} \end{aligned}$$
Propane in presence of $$\mathrm{O}_2$$ gas undergoes complete combustion to produce $$\mathrm{CO}_2$$ and $$\mathrm{H}_2 \mathrm{O}$$. The required $$\mathrm{O}_2$$ for this combustion reaction was produced by the electrolysis of water. For what duration of time had water been electrolysed by passing $$200 \mathrm{~A}$$ current so that Oxygen gas produced could completely burn $$44 \mathrm{~g}$$ of Propane?
$$0.1 \mathrm{M}$$ solution of $$\mathrm{AgNO}_3$$ is taken in a Conductivity cell and a potential difference of $$40 \mathrm{~V}$$ is applied across the ends of a column of this solution whose diameter is $$4.0 \mathrm{~cm}$$ and length of the column is $$12 \mathrm{~cm}$$. The current used is $$0.4 \mathrm{~A}$$. The Molar conductivity of the solution is _________.
Match the chemical reactions taking place at the Anode of the cell with the correct cell in which the reaction occurs.
No. | Anodic reaction | No. | Cell |
---|---|---|---|
A | $$ \mathrm{Zn}(\mathrm{Hg})+2 \mathrm{OH}^{-} \rightarrow \mathrm{ZnO}_{(\mathrm{S})}+\mathrm{H}_2 \mathrm{O}+2 e $$ |
P | Fuel cell |
B | $$ 2 \mathrm{H}_2(g)+4 \mathrm{OH}^{-} \rightarrow 4 \mathrm{H}_2 \mathrm{O}(l)+4 e $$ |
Q | Leclanche cell |
C | $$ Z n_{(S)} \rightarrow Z n^{2+}+2 e $$ |
R | Nickel Cadmium storage cell |
D | $$ \mathrm{Cd}_{(S)}+2 \mathrm{OH}^{-} \rightarrow \mathrm{CdO}_{(S)}+\mathrm{H}_2 \mathrm{O}(l)+2 e $$ |
S | Mercury cell |