1
COMEDK 2023 Morning Shift
MCQ (Single Correct Answer)
+1
-0

The complex $$\left[\mathrm{PtCl}_2(\mathrm{en})_2\right]^{2+}$$ ion shows

A
structural isomerism
B
geometrical isomerism only
C
optical isomerism only
D
geometrical and optical isomerism
2
COMEDK 2023 Morning Shift
MCQ (Single Correct Answer)
+1
-0

The blue colouration obtained from the Lassaigne's test of nitrogen is due to the formation of

A
$$\mathrm{Fe}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]_3$$
B
$$\mathrm{Fe}_2\left[\mathrm{Fe}(\mathrm{CN})_6\right]_5$$
C
$$\mathrm{K}_2\left[\mathrm{Fe}(\mathrm{CN})_6\right]_5$$
D
$$\mathrm{K}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]_3$$
3
COMEDK 2023 Morning Shift
MCQ (Single Correct Answer)
+1
-0

Aqueous $$\mathrm{CuSO}_4$$ changes its colour from sky blue to deep blue on addition of $$\mathrm{NH}_3$$ because

A
$$\mathrm{Cu}^{2+}$$ forms hydrate
B
$$\mathrm{Cu}^{2+}$$ changes to $$\mathrm{Cu}^{+}$$
C
$$\left[\mathrm{Cu}\left(\mathrm{H}_2 \mathrm{O}\right)_4\right]^{2+}$$ is labile complex and changes to $$\left[\mathrm{Cu}\left(\mathrm{NH}_3\right)_4\right]^{2+}$$ as $$\mathrm{NH}_3$$ is stronger ligand than $$\mathrm{H}_2 \mathrm{O}$$
D
$$\mathrm{Cu}^{+}$$ changes to $$\mathrm{Cu}^{2+}$$
4
COMEDK 2023 Morning Shift
MCQ (Single Correct Answer)
+1
-0

Which of the following complex show optical isomerism?

(i) $$c i s-\left[\mathrm{COCl}(\mathrm{en})_2\left(\mathrm{NH}_3\right)\right]^{2+}$$

(ii) $$cis-\left[\mathrm{CrCl}_2(\mathrm{ox})_2\right]^{3-}$$

(iii) $$cis-[ \left.\mathrm{CO}(\mathrm{en})_2 \mathrm{Cl}_2\right] \mathrm{Cl}$$

(iv) $$cis- \left[\mathrm{CO}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right]^{+}$$

A
(i), (ii), (iii)
B
(i), (ii)
C
(i), (iv)
D
(i), (ii), (iv)
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