1
COMEDK 2026 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0

Identify the complex which exhibits all 3 characteristics; paramagnetic; high spin configuration; octahedral geometry

A

$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{Cl}_2$

B

$\left[\mathrm{Ni}\left(\mathrm{H}_2 \mathrm{O}\right)_2\left(\mathrm{C}_2 \mathrm{O}_4\right)_2\right]^{2-}$

C

$\left[\mathrm{CO}\left(\mathrm{NH}_3\right)(\mathrm{Cl})(\mathrm{en})_2\right]^{2+}$

D

$\left[\mathrm{Ni}(\mathrm{CO})_4\right]$

2
COMEDK 2026 Morning Shift
MCQ (Single Correct Answer)
+1
-0

$$ \text { Match the Coordination compounds in Column I with the type of stereoisomerism given in Column II exhibited by them. } $$

$$
\text { Column I }
$$
$$
\text { Column I }
$$
A $$
\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}_2\right]
$$
P fac-mer
B $$
\mathrm{Ni}\left[\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}_2\right]
$$
Q cis -trans
C $$
\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3\left(\mathrm{NO}_2\right)_3\right]
$$
R only cis isomer shows optical isomerism
D $$
\left[\mathrm{Pt} \mathrm{Cl}_2(\mathrm{en})_2\right]^{2+}
$$
S does not exhibit isomerism.
A

$$ A-S \quad B-R \quad C-Q \quad D-P $$

B

$$ A-S \quad B-P \quad C-Q \quad D-R $$

C

$$ A-Q \quad B-S \quad C-O \quad D-R $$

D

$$ A-R \quad B-P \quad C-S \quad D-Q $$

3
COMEDK 2026 Morning Shift
MCQ (Single Correct Answer)
+1
-0

The Crystal Field Stabilisation energy of (i) $\left[\mathrm{CoF}_6\right]^{3-}$ and (ii) $\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}$ are ⋯and ⋯⋯ respectively.

A

(i) $-2.8 \Delta_0$         (ii) $-2.4 \Delta_0$

B

(i) $2.8 \Delta_0$        (ii) $2.4 \Delta_0$

C
(i) $-0.6 \Delta_0$        (ii) $0.4 \Delta_0$
D
(i) $-0.4 \Delta_0$         ii) $0 \Delta_0$
4
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Arrange the complex ions in the increasing order of their magnetic moments

A. $\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$
B. $\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-}$
C. $\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{3-}$
D. $\left[\mathrm{FeF}_6\right]^{3-}$

A
$\mathrm{D}<\mathrm{A}<\mathrm{B}<\mathrm{C}$
B
$\mathrm{B}<\mathrm{C}<\mathrm{A}<\mathrm{D}$
C
$\mathrm{D}<\mathrm{C}<\mathrm{B}<\mathrm{A}$
D
$\mathrm{A}<\mathrm{D}<\mathrm{C}<\mathrm{B}$

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