Identify the complex which exhibits all 3 characteristics; paramagnetic; high spin configuration; octahedral geometry
$$ \text { Match the Coordination compounds in Column I with the type of stereoisomerism given in Column II exhibited by them. } $$
| $$ \text { Column I } $$ |
$$ \text { Column I } $$ |
||
|---|---|---|---|
| A | $$ \left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}_2\right] $$ |
P | fac-mer |
| B | $$ \mathrm{Ni}\left[\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}_2\right] $$ |
Q | cis -trans |
| C | $$ \left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3\left(\mathrm{NO}_2\right)_3\right] $$ |
R | only cis isomer shows optical isomerism |
| D | $$ \left[\mathrm{Pt} \mathrm{Cl}_2(\mathrm{en})_2\right]^{2+} $$ |
S | does not exhibit isomerism. |
The Crystal Field Stabilisation energy of (i) $\left[\mathrm{CoF}_6\right]^{3-}$ and (ii) $\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}$ are ⋯and ⋯⋯ respectively.
Arrange the complex ions in the increasing order of their magnetic moments
A. $\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$
B. $\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-}$
C. $\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{3-}$
D. $\left[\mathrm{FeF}_6\right]^{3-}$
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