With reference to the two statements Assertion and Reason, choose the correct option.

Assertion: The order of reactivity towards $\mathrm{S}_{\mathrm{N}} 1$ reaction is: $\mathrm{C}_6 \mathrm{H}_5-\mathrm{CH}_2 \mathrm{Br}>\left(\mathrm{CH}_3\right)_3-\mathrm{C}-\mathrm{Br}>\left(\mathrm{CH}_3\right)_2-\mathrm{CH}-\mathrm{Br}$.

Reason: Among the given 3 compounds, the Benzyl carbocation formed is the most stable while Isopropyl carbocation is the least stable one.

Identify the wrong statement from the following

Select the reagents needed to convert Benzene to 4-Bromophenylpropene in the correct sequential order.

(A). $\mathrm{Cl}_2 / \Delta$

(B). $\left(\mathrm{CH}_3\right)_2-\mathrm{CHCl}$ /anhyd. $\mathrm{AlCl}_3$

(C). Alc. KOH

(D). $\mathrm{Br}_2 / \mathrm{Fe}$

Two statements, Assertion and Reason are given. With reference to them, choose the correct option.

Assertion: Hydrolysis of 2-Bromo-2-methylpropane follows $S_N 1$ mechanism which involves 2 steps and the first step is:

Reason: The energy required to cleave $\mathrm{C}-\mathrm{Br}$ is taken from the energy released due to Inductive effect and hyper-conjugative effect.