1
COMEDK 2024 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Two statements, Assertion and Reason are given below. Choose the correct option.

Assertion: n-propyl tert-butyl ether can be readily prepared in the laboratory by Williamson's synthesis.

Reason: The reaction occurs by $$\mathrm{S}_{\mathrm{N}} 1$$ attack of Primary alkoxide on Tert-alkyl halide to give good yield of the product, n-propyl tert-butyl ether.

A
Assertion is incorrect bur reason is correct.
B
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion.
C
Assertion is correct but Reason is incorrect.
D
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion.
2
COMEDK 2024 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Compounds $$\mathrm{A}$$ and $$\mathrm{B}$$, having the same molecular formula $$(\mathrm{C}_4 \mathrm{H}_8 \mathrm{O})$$, react separately with $$\mathrm{CH}_3 \mathrm{MgBr}$$, followed by reaction with dil. $$\mathrm{HCl}$$ to form compounds $$\mathrm{X}$$ and $$\mathrm{Y}$$ respectively. Compound $$\mathrm{Y}$$ undergoes acidic dehydration in presence of Conc. $$\mathrm{H}_2 \mathrm{SO}_4$$ much more readily than $$\mathrm{X}$$. Compound $$\mathrm{Y}$$ also reacts with Lucas reagent, much more readily than $$\mathrm{X}$$, with appearance of turbidity. Identify $$\mathrm{X}$$ and $$\mathrm{Y}$$.

A
$$ \mathrm{X}=\text { Pentan }-1-\mathrm{ol} \quad \mathrm{Y}=\text { Pentan }-2-\mathrm{ol} $$
B
$$ \mathrm{X}=\text { Butan-2-ol } \quad \mathrm{Y}=\text { 2-Methylpropan-2-ol } $$
C
$$ \mathrm{X}=\text { Pentan-1-ol } \quad \mathrm{Y}=2-\text { Methylpentan-2-ol } $$
D
$$ \mathrm{X}=\text { Pentan-2-ol } \quad \mathrm{Y}=2 \text {-Methylbutan-2-ol } $$
3
COMEDK 2024 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0

The major product '$$\mathrm{X}$$' of the following reaction is

COMEDK 2024 Afternoon Shift Chemistry - Alcohol, Phenols and Ethers Question 16 English

A
3, 3-dimethylpent-1-ene
B
3, 4-dimethylpent-1-ene
C
2, 3-dimethylpent-2-ene
D
3-methylpent-2-ene
4
COMEDK 2024 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0

Which of the following tests may be used to distinguish between phenol and cyclohexanol?

A
Hinsberg test
B
Ferric chloride test
C
Reaction with Na metal
D
Iodoform test
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