1
COMEDK 2024 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0

Arrange the following compounds in the decreasing order of their acidic strength.

(I) m-cresol

(II) Phenol

(III) m-aminophenol

(IV) m-methoxyphenol

A
I > III > IV > II
B
I > II > III > IV
C
IV > III > II > I
D
III > I > II > IV
2
COMEDK 2024 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0

Which of the following compound cannot be prepared by Williamson's synthesis?

A
$$\mathrm{C}_6 \mathrm{H}_5 \mathrm{OCH}_2 \mathrm{CH}_3$$
B
$$\left(\mathrm{C}_2 \mathrm{H}_5\right)_2 \mathrm{O}$$
C
$$\left(\mathrm{CH}_3\right)_3 \mathrm{COC}\left(\mathrm{CH}_3\right)_3$$
D
$$\left(\mathrm{CH}_3\right)_3 \mathrm{COCH}_2 \mathrm{CH}_3$$
3
COMEDK 2024 Morning Shift
MCQ (Single Correct Answer)
+1
-0

An organic compound $$[\mathrm{A}]\left(\mathrm{C}_5 \mathrm{H}_{12} \mathrm{O}\right)$$, on reaction with conc. $$\mathrm{H}_2 \mathrm{SO}_4$$ at $$443 \mathrm{~K}$$ gives $$[\mathrm{B}]$$ as one of the products. Compound [B] undergoes further reaction with $$\mathrm{O}_3$$ and $$\mathrm{Zn} / \mathrm{H}_2 \mathrm{O}$$ to give Propanone and Ethanal as products. Identify compound [A]

A
Pentan-2-ol
B
Pentan-1-ol
C
3-Methylbutan-2-ol
D
2- Methylbutan-1-ol
4
COMEDK 2024 Morning Shift
MCQ (Single Correct Answer)
+1
-0

Match the compounds given in column I with the corresponding most stable Carbocations formed by each, as given in Column II, when they undergo acidic dehydration in presence of Conc. $$\mathrm{H}_2 \mathrm{SO}_4$$.

No. Column I No. Column II
A 2-Methylbutan-1-ol P $${(C{H_3})_2}\mathop C\limits^ + - CH{(C{H_3})_2}$$
B Butan-2-ol Q $$C{H_3} - C{H_2} - C{H_2} - \mathop C\limits^ + {H_2}$$
C 3, 3-Dimethylbutan-2-ol R $${(C{H_3})_2}\mathop C\limits^ + - C{H_2} - C{H_3}$$
D Butan-1-ol S $$C{H_3} - \mathop C\limits^ + H - C{H_2} - C{H_3}$$

A
$$ \mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{R} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{P} $$
B
$$ \mathrm{A}=\mathrm{Q} \quad \mathrm{B}=\mathrm{R} \quad \mathrm{C}=\mathrm{S} \quad \mathrm{D}=\mathrm{P} $$
C
$$ \mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{S} \quad \mathrm{C}=\mathrm{P} \quad \mathrm{D}=\mathrm{Q} $$
D
$$ \mathrm{A}=\mathrm{Q} \quad \mathrm{B}=\mathrm{S} \quad \mathrm{C}=\mathrm{P} \quad \mathrm{D}=\mathrm{R} $$
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