1
COMEDK 2024 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0

The half-life for a zero order reaction is

A
Inversely proportional to the initial concentration and directly proportional to the rate constant
B
Directly proportional to the initial concentration and inversely proportional to the rate constant
C
Independent of rate constant, but depends on the initial concentration
D
Independent of initial concentration
2
COMEDK 2024 Morning Shift
MCQ (Single Correct Answer)
+1
-0

The time required for $$80 \%$$ of a first order reaction is "$$y$$" times the half-life period of the same reaction. What is the value of "$$y$$"?

A
3.22
B
2.32
C
0.322
D
2.96
3
COMEDK 2024 Morning Shift
MCQ (Single Correct Answer)
+1
-0

The rate constant for the reaction $$\mathrm{A} \rightarrow \mathrm{B}+\mathrm{C}$$ at $$500 \mathrm{~K}$$ is given as $$0.004 \mathrm{~s}^{-1}$$. At what temperature will the rate constant become $$0.014 \mathrm{~s}^{-1}$$ ? $$\mathrm{E}_{\mathrm{a}}$$ for the reaction is $$18.231 \mathrm{~kJ}$$.

A
950 K
B
597 K
C
700 K
D
800 K
4
COMEDK 2024 Morning Shift
MCQ (Single Correct Answer)
+1
-0

For the reaction $$\mathrm{Cl}_{2(\mathrm{~g})}+2 \mathrm{NO}_{(\mathrm{g})} \rightarrow 2 \mathrm{NOCl}_{(\mathrm{g})}$$, the following data was obtained:

Experiment No. Initial concentration of $$\mathrm{Cl_2}$$ ($$\mathrm{M}$$) Initial concentration of $$\mathrm{NO}$$ ($$\mathrm{M}$$) Initial reaction rate ($$\mathrm{M}$$/min)
I 0.15 0.15 0.60
II 0.30 0.15 1.20
III 0.15 0.3 2.40
IV 0.25 0.25 2.78

Identify the order of the reaction with respect to $$\mathrm{Cl}_2, \mathrm{NO}$$ and the value of Rate constant.

A
$$ \text { Order with respect to } \mathrm{Cl}_2=2 \quad \text { Order with respect to } \mathrm{NO}=1 \quad \mathrm{k}=355.5 \mathrm{~mol}^{-2} \mathrm{~L}^2 \mathrm{~min}^{-1} $$
B
$$ \text { Order with respect to } \mathrm{Cl}_2=0 \quad \text { Order with respect to } \mathrm{NO}=1 \quad \mathrm{k}=8.0 \mathrm{~min}^{-1} $$
C
$$ \text { Order with respect to } \mathrm{Cl}_2=1 \quad \text { Order with respect to } \mathrm{NO}=2 \quad \mathrm{k}=177.7 \mathrm{~mol}^{-2} \mathrm{~L}^2 \mathrm{~min}^{-1} $$
D
$$ \text { Order with respect to } \mathrm{Cl}_2=1 \quad \text { Order with respect to } \mathrm{NO}=1 \quad \mathrm{k}=26.66 \mathrm{~mol}^{-1} \mathrm{Lmin}^{-1} $$
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