1
COMEDK 2023 Evening Shift
MCQ (Single Correct Answer)
+1
-0

A first order reaction proceeds to $$90 \%$$ completion. What will be the approximate time taken for $$90 \%$$ completion in relation to $$t_{1 / 2}$$ of the reaction?

A
5.02 times of $$\mathrm{t}_{1 / 2}$$
B
4.54 times of $$\mathrm{t}_{1 / 2}$$
C
5.66 times of $$\mathrm{t}_{1 / 2}$$
D
3.32 times of $$\mathrm{t}_{1 / 2}$$
2
COMEDK 2023 Evening Shift
MCQ (Single Correct Answer)
+1
-0

For a reaction of the type, $$2 \mathrm{X}+\mathrm{Y} \rightarrow \mathrm{A}+\mathrm{B}$$, the following is the data collected:

Experiment $$\mathrm{[X]}$$ $$\mathrm{[Y]}$$ Initial rate of formation of A
1 0.2 0.2 $$12.0\times10^{-3}$$
2 0.6 0.4 $$\mathrm{14.4\times10^{-2}}$$
3 0.6 0.8 $$5.76\times10^{-1}$$
4. 0.8 0.2 $$\mathrm{4.8\times10^{-2}}$$

What is the overall order of the reaction?

A
2.5
B
3
C
2
D
1.5
3
COMEDK 2023 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Match the details given in Column I with those given in Column II

S.No. Column I S.No. Column II
A For complex reactions order is determined by P Rate of reaction.
B For Zero order reaction unit of $\mathrm{k}$ is same as that of Q Slope $$=k/2.303$$
C Mathematical expression which gives relationship between rate of reaction and concentrations of reactants is called R Slowest rate determining step.
D For a first order reaction plot of $$\mathrm{\log \left[R_0\right] /[R]}$$ vs time gives S Rate law.

A
$$ \mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{R} \quad \mathrm{C}=\mathrm{P} \quad \mathrm{D}=\mathrm{Q} $$
B
$$ \mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{R} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{P} $$
C
$$ \mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{P} \quad \mathrm{C}=\mathrm{S} \quad \mathrm{D}=\mathrm{Q} $$
D
$$ \mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{S} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{P} $$
4
COMEDK 2023 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Given below are graphs showing the variation in velocity constant with temperature on Kelvin scale. Identify the graph which represents Arrhenius equation.

COMEDK 2023 Evening Shift Chemistry - Chemical Kinetics Question 11 English

A
D
B
C
C
A
D
B
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