1
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0

(i) and (ii) are 2 chemical reactions carried out at TK.

(i). $\mathrm{X} \rightarrow \mathrm{Y}+\mathrm{W}$ with $\mathrm{k}_1$ as rate constant.

(ii). $\mathrm{X} \rightarrow \mathrm{Z}+\mathrm{W}$ with $k_2$ as rate constant.

The Activation energy for reaction (ii) is 3 times that of reaction (i). What is the expression for $k_1$ ?

A
$k_1=-2 k_2 e^{2 E a_1 / R T}$
B
$k_1=k_2 e^{2 E a_1 / R T}$
C
$k_1=2 k_2 e^{E a_1 / R T}$
D
$k_1=k_2 / 2 e^{-E a_1 / R T}$
2
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0
The rate constant for a zero order reaction $\mathrm{A} \rightarrow \mathrm{B}+\mathrm{C}$ is $6.0 \times 10^{-3} \mathrm{molL}^{-1} \mathrm{~s}^{-1}$. What would be the time taken for the initial concentration of A to decrease from 0.2 M to 0.024 M ?
A
15.83 s
B
37.34 s
C
31.90 s
D
29.33 s
3
COMEDK 2025 Morning Shift
MCQ (Single Correct Answer)
+1
-0

Two statements, One Assertion (A) and the other Reason (R) are given. Choose the right option.

Assertion: The rate constant $(\mathrm{k})$ for a chemical reaction gets nearly doubled for a $10^0$ rise in temperature.

Reason: The number of bimolecular collisions between reactant molecules increase with increase in temperature

A
A is correct but R is wrong.
B
Both A and R are correct but R is not the correct explanation of A .
C
Both $A$ and $R$ are correct and $R$ is the correct explanation of $A$.
D
A is wrong but R is correct.
4
COMEDK 2025 Morning Shift
MCQ (Single Correct Answer)
+1
-0
Two chemical reactions of the same order have equal Frequency factor value. Their Activation energies differ by $26.8 \mathrm{~kJ} / \mathrm{mol}$. At 300 K if $k_2=x k_1$ find the value of $x$.
A
$4.631 \times 10^4$
B
$1.143 \times 10^3$
C
$2.286 \times 10^3$
D
4.665
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