Choose the incorrect statement from the following.

An organic compound $[\mathrm{X}]$ reacts with $\mathrm{H}_2 / \mathrm{Pd}-\mathrm{BaSO}_4$ to give compound $[\mathrm{Y}]$ which reduces Tollen's reagent and undergoes Cannizzaro's reaction. On rigorous oxidation of $[\mathrm{Y}]$ in presence of $\mathrm{KMnO}_4 / \mathrm{H}^{+}$Phthalic acid is the product obtained. What is $[\mathrm{X}]$ ?

Two statements, one Assertion (A) and the other Reason (R) are given. Choose the correct option.

Assertion: 2-aminoethanoic acid and p-aminobenzene sulphonic acid can exist as Zwitter ions while p-aminobenzoic acid cannot.

Reason: When the acid group is a relatively strong proton donor and the $-\mathrm{NH}_2$ group is sufficiently basic it can accept a $\mathrm{H}^{+}$ion from the acid group to form the dipolar ion.

Two statements, One Assertion [ A ] and the other Reason [ R ] are given. Identify the correct option

Assertion $[A]$ : The decreasing order of the acidic character of the following is $B>D>A>C$

Reason $[\mathbf{R}]$ : Fluorine has larger -I effect than Cl and Br .