1
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0
An organic compound $\mathrm{A}\left(\mathrm{C}_5 \mathrm{H}_9 \mathrm{~N}\right)$ upon reaction with $\mathrm{Na} / \mathrm{Hg} / \mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}$ gives compound B . B reacts with $\mathrm{NaNO}_2 / \mathrm{HCl}$ at 274 K to form C with quantitative liberation of $\mathrm{N}_2$ gas. B also reacts with Hinsberg's reagent to form a compound which is soluble in alkali. Identify compound B.
A
$\left[\left(\mathrm{CH}_3\right)_3-\mathrm{N}-\mathrm{CH}_2 \mathrm{CH}_3\right]^{+}$
B
$\mathrm{CH}_3-\left(\mathrm{CH}_2\right)_3-\mathrm{NH}-\mathrm{CH}_3$
C
$\mathrm{CH}_3-\left(\mathrm{CH}_2\right)_4-\mathrm{NH}_2$
D
$\mathrm{CH}_3-\left(\mathrm{CH}_2\right)_2-\mathrm{N}-\left(\mathrm{CH}_3\right)_2$
2
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0

Identify the product $(\mathrm{Y})$ formed in the given reaction and the name of the reaction where $(\mathrm{X}) \rightarrow(\mathrm{Y})$.

A
$Y=$ Ethoxybenzene $\quad$ Wurtz-Fittig reaction
B
$\mathrm{Y}=$ Diphenyl $\quad$ Fittig reaction
C
$\mathrm{Y}=1,4$ - Diiodobenzene $\quad$ Wurtz reaction
D
$Y=$ Iodobenzene $\quad$ Sandmeyer's reaction
3
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0
Choose the correct statement:
A
Aliphatic amines are weaker bases than $\mathrm{NH}_3$ while aromatic amines are stronger bases than $\mathrm{NH}_3$.
B
Gabriel phthalimide synthesis is used for preparing both Ethyl amine and Aniline.
C
Anilinium ion is less resonance stabilised than Aniline.
D
Sec-butylamine is optically inactive because Nitrogen atom of the $-\mathrm{NH}_2$ group is achiral.
4
COMEDK 2025 Morning Shift
MCQ (Single Correct Answer)
+1
-0
An organic compound $[\mathrm{X}]$ (molecular formula- $\mathrm{C}_5 \mathrm{H}_{11} \mathrm{NO}$ when reacted with $\mathrm{Br}_2$ / aq. NaOH yielded $[\mathrm{Y}]$ which reacts with $\mathrm{CHCl}_3$ and Ethanolic KOH to produce a foul smelling compound. Compound $[\mathrm{Y}]$ also reacts with HONO to produce Butan-1-ol with liberation of $\mathrm{N}_2(\mathrm{~g})$. Identify [X].
A
$\mathrm{CH}_3-\left(\mathrm{CH}_2\right)_3-\mathrm{CONH}_2$
B
$\mathrm{CH}_3-\left(\mathrm{CH}_2\right)_2-\mathrm{CO}-\mathrm{CH}_2-\mathrm{NH}_2$
C
$\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{CO}-\left(\mathrm{CH}_2\right)_2-\mathrm{NH}_2$
D
$\mathrm{CH}_3-\left(\mathrm{CH}_2\right)_2-\mathrm{CH}\left(\mathrm{NH}_2\right)-\mathrm{CHO}$
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