1
COMEDK 2024 Morning Shift
MCQ (Single Correct Answer)
+1
-0

Given: $$\Delta \mathrm{G}^0{ }_{\mathrm{f}}$$ of $$\mathrm{C}_2 \mathrm{H}_2$$ is $$2.09 \times 10^5 \mathrm{~J} / \mathrm{mol}$$ and $$\Delta \mathrm{G}_{\mathrm{f}}^0$$ of $$\mathrm{C}_6 \mathrm{H}_6$$ is $$1.24 \times 10^5 \mathrm{~J} / \mathrm{mol}$$. Calculate the equilibrium constant for the cyclic polymerisation of Ethyne to Benzene at $$27^{\circ} \mathrm{C}$$. $$(\mathrm{R}=8.314 \mathrm{JK}^{-1} \mathrm{~mol}^{-1})$$

A
$$1.1134\times10^{10}$$
B
0.1113
C
$$1.429\times10^{88}$$
D
88.15
2
COMEDK 2024 Morning Shift
MCQ (Single Correct Answer)
+1
-0

If the enthalpy of formation of a diatomic molecule $$\mathrm{AB}$$ is $$-400 \mathrm{~kJ} / \mathrm{mol}$$ and the bond dissociation energies of $$\mathrm{A}_2$$ and $$\mathrm{B}_2$$ and $$\mathrm{AB}$$ are in the ratio $$2: 1: 2$$, what is the bond dissociation enthalpy of $$\mathrm{B}_2$$ ?

A
800 kJ/mol
B
600 kJ/mol
C
1600 kJ/mol
D
400 kJ/mol
3
COMEDK 2023 Morning Shift
MCQ (Single Correct Answer)
+1
-0

If 2 moles of $$\mathrm{C}_6 \mathrm{H}_6(\mathrm{~g})$$ are completely burnt $$4100 \mathrm{~kJ}$$ of heat is liberated. If $$\Delta H^{\circ}$$ for $$\mathrm{CO}_2(\mathrm{~g})$$ and $$\mathrm{H}_2 \mathrm{O}(l)$$ are $$-410$$ and $$-285 \mathrm{~kJ}$$ per mole respectively then the heat of formation of $$\mathrm{C}_2 \mathrm{H}_6(g)$$ is

A
$$-116 \mathrm{~kJ}$$
B
$$-375 \mathrm{~kJ}$$
C
$$-775 \mathrm{~kJ}$$
D
$$-885 \mathrm{~kJ}$$
4
COMEDK 2023 Morning Shift
MCQ (Single Correct Answer)
+1
-0

For an adiabatic change in a system, the condition which is applicable is

A
$$q=0$$
B
$$w=0$$
C
$$q=-w$$
D
$$q=w$$
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