Gaseous Nitrous oxide decomposes at $$298 \mathrm{~K}$$ to form Nitrogen gas and Oxygen gas. The $$\Delta \mathbf{H}$$ for the reaction at $$1.0 \mathrm{~atm}$$ pressure and $$298 \mathrm{~K}$$ is $$\mathbf{- 1 6 3 . 1 5} \mathbf{~ k J}$$. Calculate Internal energy change for the decomposition of $$100 \mathrm{~g}$$ of Nitrous oxide gas under the same conditions of temperature and pressure.

A Gas taken in a closed vessel is heated from $$54^{\circ} \mathrm{C}$$ to $$1254^{\circ} \mathrm{C}$$. The pressure of the gas becomes ___________ times its original pressure $$\mathrm{P_1}$$

Which of the following are not path functions?

I. H $$-$$ TS

II. W

III. q

IV. q + W

The relation between work done in reversible and irreversible process is