Which of the following set of thermodynamic conditions is true for the reaction to be spontaneous at high temperature?

Calculate the energy per mole of photon of electromagnetic radiation having wavelength $700 \mathrm{~nm}\left[\mathrm{~h}=6.626 \times 10^{-34} \mathrm{Js}, \mathrm{c}=3 \times 10^8 \mathrm{~m} / \mathrm{s}\right]$

Which of the following molecules consist minimum lone pair of electrons in the valence shell of central atom?