What is the approximate molality of $10 \%(w / w)$ aqueous glucose solution?

(Molar mass of glucose $=180 \mathrm{~g} \mathrm{~mol}^{-1}$ )

The van't Hoff factor for 0.5 m aqueous $\mathrm{CH}_2 \mathrm{FCOOH}$ solution is 1.075 . What is the experimentally observed $\Delta T_f$ (in K ) for this solution?

( $K_f=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$ )

An aqueous solution containing 0.2 g of a non volatile solute ' $A$ ' in 21.5 g of water freezes at 272.814 K . If the freezing point of water is 273.16 K , the molar mass (in $\mathrm{g} \mathrm{mol}^{-1}$ ) of solute $A$ is $\left[\mathrm{K}_f\left(\mathrm{H}_2 \mathrm{O}\right)=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right]$

At $T(\mathrm{~K})$, the vapour pressure of $x$ molal aqueous solution containing a non-volatile solute is $12.078 \mathrm{kPa}_{\mathrm{d}}$, The vapour pressure of pure water at $T(\mathrm{~K})$ is 12.3 kPa . What is the value of $x$ ?