1
AP EAPCET 2025 - 23rd May Morning Shift
MCQ (Single Correct Answer)
+1
-0
A solution of urea in water has a boiling point or $100.18^{\circ} \mathrm{C}$. What is the freezing point of the same solution, if $K_f$ and $K_b$ of water are 1.86 and 0.52 K kg $\mathrm{mol}^{-1}$.
A

$-0.34^{\circ} \mathrm{C}$

B

$-022^{\circ} \mathrm{C}$

C

$-0.64^{\circ} \mathrm{C}$

D

$-0.32^{\circ} \mathrm{C}$

2
AP EAPCET 2025 - 23rd May Morning Shift
MCQ (Single Correct Answer)
+1
-0

At $T(\mathrm{~K})$, the vapour pressure of pure benzene and toluene are 75 and 22 mm Hg respectively. 23.4 g of benzene and 64.4 g of toluene are mixed to form an ideal solution. If the vapours are in equilibrium with the liquid mixture, the mole fraction of toluene in vapour phase (At.wt. of $\mathrm{C}=12, \mathrm{H}=1$ )

A

0.406

B

0.594

C

0.539

D

0.461

3
AP EAPCET 2025 - 22nd May Evening Shift
MCQ (Single Correct Answer)
+1
-0

1.95 g of non-volatile and non-electrolyte solute dissolved in 100 g of benzene lowered the freezing point of it by 0.64 K .

The molar mass of the solute (in $\mathrm{g} \mathrm{mol}^{-1}$ )

$$ \left(K_f\left(\mathrm{C}_6 \mathrm{H}_6\right)=5.12 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right) $$

A

240

B

156

C

165

D

265

4
AP EAPCET 2025 - 22nd May Evening Shift
MCQ (Single Correct Answer)
+1
-0

At $298 \mathrm{~K}, 0.714$ moles of liquid $A$ is dissolved in 5.555 moles of liquid $B$. The vapour pressure of the resultant solution is 475 torr. The vapour pressure of pure liquid $A$ at the same temperature is 280.7 torr. What is the vapour pressure of pure liquid $B$ in torr?

A

486

B

550

C

514

D

500

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