Ionic Equilibrium · Chemistry · AP EAPCET

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MCQ (Single Correct Answer)

1

At $T(\mathrm{~K}) K_{\mathrm{sp}}$ of two ionic salts $M X_2$ and $M X$ is $5 \times 10^{-13}$ and $1.6 \times 10^{-11}$ respectively. The ratio of molar solubility of $M X_2$ and $M X$ is

AP EAPCET 2025 - 27th May Morning Shift
2

The molar solubility of $\mathrm{PbI}_2$ in $0.2 \mathrm{MPb}\left(\mathrm{NO}_3\right)_2$ solution in terms of $K_{s p}$ (solubility product) is

AP EAPCET 2025 - 26th May Evening Shift
3

The percentage of ionisation of 1 L of $x \mathrm{M}$ acetic acid is 4.242 and is called solution " $A$ ". The percentage of ionisation of 1 L of $y \mathrm{M}$ acetic acid is 3 and is called solution " $B$ ". Solution " $A$ " is mixed with solution " $B$ ". What is the concentration of acetic acid in the resultant solution? ( $K_{\mathrm{a}}$ of acetic acid $=1.8 \times 10^{-5}$ )

AP EAPCET 2025 - 23rd May Evening Shift
4
When 30 mL of $0.2 \mathrm{M} \mathrm{NH}_4 \mathrm{OH}$ is added to 30 mL of $2 \mathrm{M} \mathrm{NH}_4 \mathrm{Cl}$ solution. If the pH of the buffer formed is 8.2, what is the $\mathrm{p} K_b$ of $\mathrm{NH}_4 \mathrm{OH}$ ?
AP EAPCET 2025 - 23rd May Morning Shift
5

At $25^{\circ} \mathrm{C}, K_a$ of formic acid is $1.8 \times 10^{-4}$. What is the $K_b$ of $\mathrm{HCOO}^{-}$?

AP EAPCET 2025 - 22nd May Evening Shift
6

At $25^{\circ} \mathrm{C}$, the percentage of ionisation of ' $x$ ' M acetic acid is 4.242 . What is the value of $x$ ? $\left(K_{\mathrm{a}}=1.8 \times 10^{-5}\right)$

AP EAPCET 2025 - 22nd May Morning Shift
7

At $25^{\circ} \mathrm{C}$, the percentage of ionisation of $x \mathrm{M}$ acetic acid is 4.242 . What is the pH of the acetic acid solution?

$$ \begin{aligned} & (\log 4.242=0.6275) ;(\log 0.04242=-1.372) \\ & \left(K_{\mathrm{a}}=1.8 \times 10^{-5}\right) \end{aligned} $$

AP EAPCET 2025 - 21st May Evening Shift
8

At $T(\mathrm{~K})$, the solubility product of AgBr is $4 \times 10^{-13}$. What is its solubility in 0.1 M KBr solution?

AP EAPCET 2025 - 21st May Morning Shift
9
At $27^{\circ} \mathrm{C}$, the degree of dissociation of $\mathrm{H} A$ (weak acid) in 0.5 M of its solution is $1 \%$. The concentrations of $\mathrm{H}_3 \mathrm{O}^{+}, A^{-}$and $\mathrm{H} A$ at equilibrium (in $\mathrm{mol} \mathrm{L}^{-1}$ ) are respectively.
AP EAPCET 2024 - 23th May Morning Shift
10
100 mL of $0.1 \mathrm{M} \mathrm{H} A$ (weak acid) and 100 mL of 0.2 M $\mathrm{Na} A$ are mixed. What is the pH of resultant solution? ( $K_{\mathrm{a}}$ of $\mathrm{H} A$ is $10^{-5}: \log 2=0.3$ )
AP EAPCET 2024 - 22th May Evening Shift
11

Which of the following when added to 20 mL of a 0.01 M solution of HCl would decrease its pH ?

AP EAPCET 2024 - 22th May Morning Shift
12

The solubility of barium phosphate of molar mass ' $M$ ' $\mathrm{g} \mathrm{mol}^{-1}$ in water is $x \mathrm{~g}$ per 100 mL at 298 K . Its solubility product is $1.08 \times\left(\frac{x}{M}\right)^a \times(10)^b$. The values of $a$ and $b$ respectively are

AP EAPCET 2024 - 21th May Evening Shift
13
At $T(\mathrm{~K})$, the solubility product of $A X$ is $10^{-10}$. What is the molar solubility of $A X$ in 0.1 MHX ?
AP EAPCET 2024 - 21th May Morning Shift
14
Which of the following will make a basic buffer solution?
AP EAPCET 2024 - 20th May Evening Shift
15
At $27^{\circ} \mathrm{C}, 100 \mathrm{~mL}$ of 0.4 M HCl is mixed with 100 mL of 0.5 M NaOH solution. To the resultant solution, 800 mL of distilled water is added. What is the pH of final solution?
AP EAPCET 2024 - 20th May Morning Shift
16
What is the conjugate base of chloric acid?
AP EAPCET 2024 - 19th May Evening Shift
17

The pH of 0.01 N lime water is

AP EAPCET 2022 - 4th July Evening Shift
18

Equal volumes of 0.5 N acetic acid and 0.5 N sodium acetate are mixed. What is the pH of resultant solution? ($$\mathrm{p} K_a$$ of acetic acid $$=4.75$$)

AP EAPCET 2022 - 4th July Morning Shift
19

Match the following columns.

Column I
(Species)
Column II
(Conjugate acid)
A. NH$$_3$$ 1. H$$_2$$CO$$_3$$
B. HCO$$_3^-$$ 2. H$$_3$$O$$^+$$
C. H$$_2$$O 3. NH$$_4^+$$
D. HSO$$_4^-$$ 4. H$$_2$$SO$$_4$$

AP EAPCET 2021 - 20th August Evening Shift
20

The pH of 0.1 M solution of acetic acid will be [degree of dissociation of acetic acid is 0.0132]

AP EAPCET 2021 - 20th August Evening Shift
21

The solubility of $$\operatorname{AgBr}(s)$$, having solubility product $$5 \times 10^{-10}$$ in $$0.2 \mathrm{~M} \mathrm{~NaBr}$$ solution equals

AP EAPCET 2021 - 20th August Morning Shift
22

Calculate the pOH of 0.10 M HCl solution.

AP EAPCET 2021 - 19th August Evening Shift
23

Which among the following pairs is not an acidic buffer?

AP EAPCET 2021 - 19th August Evening Shift