If two liquids $$A$$ and $$B$$ form a minimum boiling azeotrope at some specific composition, then which statement among the following is correct?

The vapour pressure of a solvent decreased by 20 mm of Hg when a non-volatile solute was added to the solvent. The mole fraction of the solute in the solution is 0.5. What should be the mole fraction of the solvent for the decrease in the vapour pressure needs to be 10 mm of Hg?

If the $$K_{\mathrm{H}}$$ values for $$\operatorname{Ar}(g), \mathrm{CO}_2(g), \mathrm{HCHO}(g)$$ and $$\mathrm{CH}_4(\mathrm{~g})$$ respectively are $$40.39,1.67, 1.83 \times 10^{-5}$$ and $$0.413$$ , then identify the correct increasing order of their solubilities.

If 500 mL of CaCl$$_2$$ solution contains 3.01 $$\times$$ 10$$^{22}$$ chloride ions, molarity of the solution will be