Solid State · Chemistry · AP EAPCET

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MCQ (Single Correct Answer)

1

A metal crystallises in simple cubic lattice. The radius of the metal atom is $x \mathrm{pm}$. What is the volume of unit cell in $\mathrm{pm}^3$ ?

AP EAPCET 2025 - 26th May Morning Shift
2

Identify the incorrect statement is regarding the interstitial compounds.

AP EAPCET 2025 - 26th May Morning Shift
3

The crystal system with edge lengths $a \neq b \neq c$ and axial angles $\alpha=\beta=\gamma=90^{\circ}$ is ' $x$ ' and number of Bravais lattices for it is ' $y$ '. $x$ and $y$ are

AP EAPCET 2025 - 27th May Morning Shift
4

A metal crystallises in simple cubic lattice. The volume of one unit cell is $6.4 \times 10^7 \mathrm{pm}^3$. What is the radius of the metal atom in pm ?

AP EAPCET 2025 - 26th May Evening Shift
5

An element occurs in the body centred cubic structure with edge length of 288 pm . The density of the element is $7.2 \mathrm{~g} \mathrm{~cm}^{-3}$. The number of atoms present in 208 g of the element is nearly

AP EAPCET 2025 - 24th May Morning Shift
6

If AgCl is doped with $1 \times 10^{-4}$ mole percent of $\mathrm{CdCl}_2$ the number of cation vacancies (in $\mathrm{mol}^{-1}$ ) is

AP EAPCET 2025 - 23rd May Evening Shift
7

An element (atomic weight $=250 \mathrm{u}$ ) crystallises in a simple cubic lattice. If the density of the unit cell is $7.2 \mathrm{~g} \mathrm{~cm}^{-3}$. What is the radius (in $\mathop {\rm{A}}\limits^{\rm{o}}$ ) of the atom of the element?

$$ \left(N_A=6.02 \times 10^{23} \mathrm{~mol}^{-1}\right) $$

AP EAPCET 2025 - 22nd May Evening Shift
8

A compound is formed by two elements $A$ and $B$. Atoms of the element $B$ (as anion) make ccp lattice and those of element $A$ (as cation) occupy all tetrahedral voids. The formula of the compound is

AP EAPCET 2025 - 22nd May Morning Shift
9

An element crystallises in bcc lattice. The atomic radius of the element is $2.598 \mathop {\rm{A}}\limits^{\rm{o}}$. What is the volume (in $\mathrm{cm}^3$ ) of one unit cell?

AP EAPCET 2025 - 21st May Evening Shift
10

Gold crystallises in fcc lattice. The edge length of the unit cell is $4 \mathop {\rm{A}}\limits^{\rm{o}}$. The closest distance between gold atoms is ' $x$ ' $\mathop {\rm{A}}\limits^{\rm{o}}$ and density of gold is ' $y$ ' $\mathrm{g} \mathrm{cm}^{-3}$. What are $x$ and $y$ respectively?

(Molar mass of gold $=197 \mathrm{~g} \mathrm{~mol}^{-1} ; N=6 \times 10^{23} \mathrm{~mol}^{-1}$ )

AP EAPCET 2025 - 21st May Morning Shift
11
The molecular formula of a cystalline solid $X_3 Y_2$. Atoms of $Y$ form ccp lattice and atoms of $X$ occupy $50 \%$ octachedral voids and $X \%$ of tetrahedral voids. What is the percentage of unoccupied tetrahedral voids?
AP EAPCET 2024 - 23th May Morning Shift
12
A compound is formed by atoms of $A, B$ and $C$. Atoms of $C$ form hcp lattice. Atoms of $A$ occupy $50 \%$ of octahedral voids and atoms of $B$ occupy $2 / 3$ rd of tetrahedral voids. What is the molecular formula of the solid?
AP EAPCET 2024 - 22th May Evening Shift
13
Zinc oxide (white) is heated to high temperature for some time. Observe the following statements regarding above process. I. Zinc oxide colour changes to pale yellow II. The type of defect formed is 'metal deficiency' III. Some $\mathrm{Zn}^{2-}$ and $\mathrm{e}^{-}$are present in interstitial place The correct statements are
AP EAPCET 2024 - 22th May Morning Shift
14
Identify the incorrect set from the following.
AP EAPCET 2024 - 21th May Evening Shift
15
What are the variables in the graph of powder diffraction pattern of a crystalline solid?
AP EAPCET 2024 - 21th May Morning Shift
16
The density of $\beta-\mathrm{Fe}$ is $7.6 \mathrm{~g} \mathrm{~cm}^{-3}$. It crystallises in cubic lattice with $\mathrm{a}=290 \mathrm{pm}$. What is the value of $Z$ ? $\left(\mathrm{Fe}=56 \mathrm{~g} \mathrm{~mol}^{-1}: N_{\mathrm{A}}=6.022 \times 10^{23} \mathrm{~mol}^{-1}\right)$
AP EAPCET 2024 - 20th May Evening Shift
17

A solid compound is formed by atoms of $A$ (cations), $B$ (cations) and O (anions). Atoms of O form hcp lattice. Atoms of $A$ occupy $25 \%$ of tetrahedral holes and atoms of $B$ occupy $50 \%$ octahedral holes. What is the molecular formula of solid?

AP EAPCET 2024 - 20th May Morning Shift
18
Which one of the following is used as piezoelectric material?
AP EAPCET 2024 - 19th May Evening Shift
19

Some substances are given below

$$ \begin{aligned} & \mathrm{Ag}, \mathrm{CO}_2(s), \mathrm{SiO}_2, \mathrm{ZnS} \\ & \mathrm{SO}_2(s), \mathrm{AlN}, \mathrm{HCl}(\mathrm{~s}), \mathrm{H}_2 \mathrm{O}(\mathrm{~s}) \end{aligned} $$

The number of molecular solids and network solids in the above list is respectively.

AP EAPCET 2024 - 19th May Evening Shift
20

The diffraction pattern of crystalline solid gave a peak at $20=60^{\circ}$. What is the distance ( in cm ) between the layers which gave this peak?

( $\lambda$ of $X$-rays is $1.54 \mathring{A}$ ) $\left(\sin 30^{\circ}=0.5, \sin 60^{\circ}=0.866 ; n=1\right)$

(a) $8.89 \times 10^{-8}$
AP EAPCET 2024 - 18th May Morning Shift
21

An element crystallising in fcc lattice has a density of $$8.92 \mathrm{~g} \mathrm{~cm}^{-3}$$ and edge length of $$3.61 \times 10^{-8} \mathrm{~cm}$$. What is the atomic weight of element? $$\left(N=6.022 \times 10^{23} \mathrm{~mol}^{-1}\right)$$

AP EAPCET 2022 - 5th July Morning Shift
22

Which of the following statement is correct for fcc lattice?

AP EAPCET 2022 - 5th July Morning Shift
23

Match List I with List II.

List - I
(Defects)
List - II
(Examples)
(A) Frenkel defects (I) FeO
(B) Schottkey defects (II) NaCl
(C) Vacancy defects (III) AgCl
(D) Metal deficiency defects (IV) Crystals with vacant lattice sites.

AP EAPCET 2022 - 4th July Evening Shift
24

Which of the following solids is not a molecular solid?

AP EAPCET 2022 - 4th July Evening Shift
25

The number of network solids and ionic solids in the list given below is respectively. $$\mathrm{H}_2 \mathrm{O}$$ (ice), $$\mathrm{AlN}, \mathrm{Cu}, \mathrm{CaF}_2$$, diamond, MgO , $$\mathrm{CCl}_4, \mathrm{ZnS}, \mathrm{Ag}, \mathrm{NaCl}, \mathrm{SiO}_2$$

AP EAPCET 2022 - 4th July Morning Shift
26

If molten NaCl contains $$\mathrm{SrCl}_2$$ as impurity, crystallisation can generate

AP EAPCET 2022 - 4th July Morning Shift
27

Photographic plates are prepared by coating emulsion of which of the following in gelatin?

AP EAPCET 2022 - 4th July Morning Shift
28

A metal crystallises with a fcc lattice, the edge of whose unit cell is $$x \mathrm{~pm}$$. The diameter of this metal atom would be .............. pm.

AP EAPCET 2021 - 20th August Evening Shift
29

In the face centered unit cell, the lattice points are present at

AP EAPCET 2021 - 20th August Morning Shift
30

The fcc crystal contains how many atoms in each unit cell?

AP EAPCET 2021 - 19th August Evening Shift