Solid State · Chemistry · AP EAPCET
MCQ (Single Correct Answer)
A metal crystallises in simple cubic lattice. The radius of the metal atom is $x \mathrm{pm}$. What is the volume of unit cell in $\mathrm{pm}^3$ ?
Identify the incorrect statement is regarding the interstitial compounds.
The crystal system with edge lengths $a \neq b \neq c$ and axial angles $\alpha=\beta=\gamma=90^{\circ}$ is ' $x$ ' and number of Bravais lattices for it is ' $y$ '. $x$ and $y$ are
A metal crystallises in simple cubic lattice. The volume of one unit cell is $6.4 \times 10^7 \mathrm{pm}^3$. What is the radius of the metal atom in pm ?
An element occurs in the body centred cubic structure with edge length of 288 pm . The density of the element is $7.2 \mathrm{~g} \mathrm{~cm}^{-3}$. The number of atoms present in 208 g of the element is nearly
If AgCl is doped with $1 \times 10^{-4}$ mole percent of $\mathrm{CdCl}_2$ the number of cation vacancies (in $\mathrm{mol}^{-1}$ ) is
An element (atomic weight $=250 \mathrm{u}$ ) crystallises in a simple cubic lattice. If the density of the unit cell is $7.2 \mathrm{~g} \mathrm{~cm}^{-3}$. What is the radius (in $\mathop {\rm{A}}\limits^{\rm{o}}$ ) of the atom of the element?
$$ \left(N_A=6.02 \times 10^{23} \mathrm{~mol}^{-1}\right) $$
A compound is formed by two elements $A$ and $B$. Atoms of the element $B$ (as anion) make ccp lattice and those of element $A$ (as cation) occupy all tetrahedral voids. The formula of the compound is
An element crystallises in bcc lattice. The atomic radius of the element is $2.598 \mathop {\rm{A}}\limits^{\rm{o}}$. What is the volume (in $\mathrm{cm}^3$ ) of one unit cell?
Gold crystallises in fcc lattice. The edge length of the unit cell is $4 \mathop {\rm{A}}\limits^{\rm{o}}$. The closest distance between gold atoms is ' $x$ ' $\mathop {\rm{A}}\limits^{\rm{o}}$ and density of gold is ' $y$ ' $\mathrm{g} \mathrm{cm}^{-3}$. What are $x$ and $y$ respectively?
(Molar mass of gold $=197 \mathrm{~g} \mathrm{~mol}^{-1} ; N=6 \times 10^{23} \mathrm{~mol}^{-1}$ )
A solid compound is formed by atoms of $A$ (cations), $B$ (cations) and O (anions). Atoms of O form hcp lattice. Atoms of $A$ occupy $25 \%$ of tetrahedral holes and atoms of $B$ occupy $50 \%$ octahedral holes. What is the molecular formula of solid?
Some substances are given below
$$ \begin{aligned} & \mathrm{Ag}, \mathrm{CO}_2(s), \mathrm{SiO}_2, \mathrm{ZnS} \\ & \mathrm{SO}_2(s), \mathrm{AlN}, \mathrm{HCl}(\mathrm{~s}), \mathrm{H}_2 \mathrm{O}(\mathrm{~s}) \end{aligned} $$
The number of molecular solids and network solids in the above list is respectively.
The diffraction pattern of crystalline solid gave a peak at $20=60^{\circ}$. What is the distance ( in cm ) between the layers which gave this peak?
( $\lambda$ of $X$-rays is $1.54 \mathring{A}$ ) $\left(\sin 30^{\circ}=0.5, \sin 60^{\circ}=0.866 ; n=1\right)$
(a) $8.89 \times 10^{-8}$An element crystallising in fcc lattice has a density of $$8.92 \mathrm{~g} \mathrm{~cm}^{-3}$$ and edge length of $$3.61 \times 10^{-8} \mathrm{~cm}$$. What is the atomic weight of element? $$\left(N=6.022 \times 10^{23} \mathrm{~mol}^{-1}\right)$$
Which of the following statement is correct for fcc lattice?
Match List I with List II.
| List - I (Defects) |
List - II (Examples) |
||
|---|---|---|---|
| (A) | Frenkel defects | (I) | FeO |
| (B) | Schottkey defects | (II) | NaCl |
| (C) | Vacancy defects | (III) | AgCl |
| (D) | Metal deficiency defects | (IV) | Crystals with vacant lattice sites. |
Which of the following solids is not a molecular solid?
The number of network solids and ionic solids in the list given below is respectively. $$\mathrm{H}_2 \mathrm{O}$$ (ice), $$\mathrm{AlN}, \mathrm{Cu}, \mathrm{CaF}_2$$, diamond, MgO , $$\mathrm{CCl}_4, \mathrm{ZnS}, \mathrm{Ag}, \mathrm{NaCl}, \mathrm{SiO}_2$$
If molten NaCl contains $$\mathrm{SrCl}_2$$ as impurity, crystallisation can generate
Photographic plates are prepared by coating emulsion of which of the following in gelatin?
A metal crystallises with a fcc lattice, the edge of whose unit cell is $$x \mathrm{~pm}$$. The diameter of this metal atom would be .............. pm.
In the face centered unit cell, the lattice points are present at
The fcc crystal contains how many atoms in each unit cell?