Coordination Compounds · Chemistry · AP EAPCET

Which of the following exhibit ionisation isomerism?

I. $\left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right] \mathrm{Cl}$

II. $\left[\mathrm{Ti}\left(\mathrm{H}_2 \mathrm{O}\right)_5 \mathrm{Cl}\right]\left(\mathrm{NO}_3\right)_2$

III. $\left[\mathrm{Pt}(\mathrm{en})\left(\mathrm{NH}_3\right) \mathrm{Cl}\right] \mathrm{NO}_3$

IV. $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4\left(\mathrm{NO}_3\right)_2\right] \mathrm{NO}_3$

Identify the set which does not have ambidentate ligand(s)

The IUPAC name of the complex shown below is $\mathrm{K}_3\left[\mathrm{Co}(\mathrm{ox})_3\right]$

The coordination number of chromium in $\mathrm{K}\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_2\left(\mathrm{C}_2 \mathrm{O}_4\right)_2\right]$ is

Identify the complex ion with spin only magnetic moment of 4.90 BM .

In which one of the following complexes the metal ion has $t_{2 g}^3 e_g^2$ configuration?

In $\mathrm{Fe}_x\left[\mathrm{Fe}_y(\mathrm{CN})_6\right]_3, x, y$ respectively, are

In which of the following, complex ions are not in correct order with respect to their magnitude of crystal field splitting?

Which of the following complexes exhibit geometrical isomerism?

I. $\left[\mathrm{Co}(\mathrm{en})\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}_2\right] \mathrm{Cl}$

II. $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right] \mathrm{Cl}$

III. $\left[\mathrm{Co}(\mathrm{en})_3, \mathrm{Cl}_3\right.$

IV. $\left[\mathrm{Co}(\mathrm{en})_2 \mathrm{Cl}_2\right] \mathrm{Br}$

Arrange the following in the increasing order of their magnetic moments

I. $\left[\mathrm{Mn}(\mathrm{CN})_6\right]^{3-}$

II. $\left[\mathrm{Mn} \mathrm{Cl}_6\right]^{3-}$

III. $\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{3-}$

IV. $\left[\mathrm{FeF}_6\right]^{3-}$

Match the complexes in List-I with their hybridisation in list-II.

Improve silver ore $+\mathrm{CN}^{-}+\mathrm{H}_2 \mathrm{O} \xrightarrow{\mathrm{O}_2}[\mathrm{X}]^{-}+\mathrm{OH}^{-}$

$$ [X]^{-}+\mathrm{Zn} \longrightarrow[Y]^{2-}+\mathrm{Ag} \text { (pure) } $$

The co-ordination numbers of the metals in $[X]$. [ $Y$ ] are respectively

How many of the following ligands are stronger than

$$ \begin{aligned} & \mathrm{H}_2 \mathrm{O} \text { ? } \\ & \mathrm{S}^{2-}, \mathrm{Br}^{-}, \mathrm{C}_2 \mathrm{O}_4^{2-}, \mathrm{CN}^{-} \text {, en, } \mathrm{NH}_3, \mathrm{CO}, \mathrm{OH}^{-} \\ & \begin{array}{ll} \text { } & \text { } \end{array} \end{aligned} $$

Arrange the following in the increasing order of number of unpaired electrons present in the central metal ion

I. $\left[\mathrm{MnCl}_6\right]^{3-}$

II. $\left[\mathrm{FeF}_6\right]^{3-}$

III. $\left[\mathrm{Mn}(\mathrm{CN})_6\right]^{3-}$

IV. $\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{3-}$

An element '$$X$$' with the atomic number 13 forms a complex of the type $$[\mathrm{XCl}(\mathrm{H}_2 \mathrm{O})_5]^{2+}$$. The covalency and oxidation state of $$X$$ in it are respectively

Identify the species, which does not exist?

The homoleptic complex in the following is

The crystal field theory is successful in explaining which of the following?

I. Ligands as point charges.

II. Formation and structures of complexes.

III. Colour.

IV. Magnetic properties.

V. Covalent character of metal-ligand bonding.

Which of the following is correct related to the colours of $$\mathrm{TiCl}_3(X)$$ and $$\left[\mathrm{Ti}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right] \mathrm{Cl}_3(Y)$$ ?

$$\mathrm{AlF}_3$$ is soluble in HF only in the presence of KF due to formation of

Potassium cyanide is made alkaline with NaOH and boiled with thiosulphate ions. The solution is cooled and acidified with HCl and this solution with iron (III) chloride produces

Which of the following complexes formed by nickel is tetrahedral and paramagnetic?

What is coordination number of the metal in $$\mathrm{{[Co{(en)_2}C{l_2}]^{2 + }}}$$ ?