p-Block Elements · Chemistry · AP EAPCET

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MCQ (Single Correct Answer)

1

The conjugate base of phosphorus acid is $x$. The conjugate base of oleum is $y$. What are $x$ and $y$, respectively?

AP EAPCET 2025 - 26th May Morning Shift
2

Consider the following

Statement-I $\mathrm{CCl}_4$ does not undergo hydrolysis. But $\mathrm{SiCl}_4$ undergoes hydrolysis.

Statement-II Thermal and chemical stability of $\mathrm{GeX}_4$ is more than $\mathrm{GeX}_2$.

The correct answer is

AP EAPCET 2025 - 26th May Morning Shift
3

Orthophosphorus acid on disproportionation gives $\mathrm{PH}_3$ and another oxoacid of phosphorus ' $X$ '. The basicity of $X$ is

AP EAPCET 2025 - 26th May Morning Shift
4

Select the correct statements from the following

(A) Aluminium liberates $\mathrm{H}_2$ gas with dil. HCl but not with aqueous NaOH .

(B) Formula of sodium metaborate is $\mathrm{Na}_3 \mathrm{BO}_3$.

(C) Boric acid is a weak monobasic acid.

(D) For thallium, +1 state is more stable than +3 state.

AP EAPCET 2025 - 27th May Morning Shift
5

The number of amphoteric oxides from the following is $\mathrm{CO}_2, \mathrm{GeO}_2, \mathrm{SnO}_2, \mathrm{PbO}_2$, $\mathrm{CO}, \mathrm{GeO}, \mathrm{SnO}, \mathrm{PbO}$

AP EAPCET 2025 - 27th May Morning Shift
6

Complete hydrolysis of xenon hexafluoride gives HF along with compound $X$. The hybridisation in $X$ is

AP EAPCET 2025 - 27th May Morning Shift
7

The correct order of electronegativity of group 13 elements is

AP EAPCET 2025 - 26th May Evening Shift
8

Identify the correct statements.

I. CO reduces the oxygen carrying ability of blood

II. Producer gas contains CO and $\mathrm{N}_2$

III. $\mathrm{C}-\mathrm{O}$ bond length in $\mathrm{CO}_2$ is 115 pm

AP EAPCET 2025 - 26th May Evening Shift
9

Observe the following

$\mathrm{P}_4+\mathrm{SOCl}_2 \rightarrow$ Products

$\mathrm{P}_4+\mathrm{SO}_2 \mathrm{Cl}_2 \rightarrow$ Products

In both the reactions, a common product ' $x$ ' is obtained. The number of lone pair of electrons on the central atom of $x$ is

AP EAPCET 2025 - 26th May Evening Shift
10

Identify the incorrect statement about silica.

AP EAPCET 2025 - 24th May Morning Shift
11

The number of $\mathrm{P}=\mathrm{O}, \mathrm{P}-\mathrm{P}$ bonds present in oxoacid of phosphorus, prepared by treating red $\mathrm{P}_4$ with alkali are respectively

AP EAPCET 2025 - 24th May Morning Shift
12

Identify the incorrect statement about the group 13 elements.

AP EAPCET 2025 - 23rd May Evening Shift
13

Which of the following statements are correct?

(I) $\mathrm{SnF}_4$ is ionic in nature.

(II) Stability of dihalides of group 14 elements increases down the group.

(III) $\mathrm{GeCl}_2$ is more stable than $\mathrm{GeCl}_4$.

AP EAPCET 2025 - 23rd May Evening Shift
14

Nature of two oxides of nitrogen $X$ and $Y$ formed in the reaction of sodium nitrite with hydrochloric acid is

AP EAPCET 2025 - 23rd May Evening Shift
15

Identify the reaction in which diborane is produced on industrial scale?

AP EAPCET 2025 - 23rd May Morning Shift
16

Which of the following is not correct?

AP EAPCET 2025 - 23rd May Morning Shift
17

Consider the following.

Statement I : $ \mathrm{Al}_2 \mathrm{O}_3$ is amphoteric in nature.

Statement II : Tl2 $\mathrm{O}_3$ is more basic than $\mathrm{Ga}_2 \mathrm{O}_3$. The correct answer is

AP EAPCET 2025 - 22nd May Evening Shift
18

White phosphorus on heating with concentrated NaOH solution in an inert atmosphere of $\mathrm{CO}_2$ gives a salt ' $X$ ' and gas ' $Y$ '. The oxidation state of central atom in $X$ and $Y$ is respectively

AP EAPCET 2025 - 22nd May Evening Shift
19

The incorrect statement from the following is

AP EAPCET 2025 - 22nd May Morning Shift
20
In Buckminster fullerene, the number of six membered carbon rings is ' $x$ ' and five membered carbon rings is ' $y$ '. $(x+y)$ value is
AP EAPCET 2025 - 22nd May Morning Shift
21

Which of the following is not correct?

AP EAPCET 2025 - 22nd May Morning Shift
22

In the structure of diborane, the number of 2-centre-2-electron bonds is $X$ and 3-centre-2-electron bonds is $Y$. The value of $(X+Y)$ is

AP EAPCET 2025 - 21st May Evening Shift
23

The oxides of nitrogen obtained by the reaction of nitric acid with (i) $\mathrm{P}_4 \mathrm{O}_{10'}$ (ii) $\mathrm{P}_4$ respectively are

AP EAPCET 2025 - 21st May Evening Shift
24

Consider the following -

Statement I : The order of electronegativity of $\mathrm{B}, \mathrm{Al}$, In Tl is $$ \mathrm{B}>\mathrm{Tl}>\mathrm{Al}>\mathrm{In} $$

Statement II : Boric acid is a weak protonic acid.

The correct answer is

AP EAPCET 2025 - 21st May Morning Shift
25

Which of the following does not exist?

AP EAPCET 2025 - 21st May Morning Shift
26

Gas $X$ is obtained in Deacon's process. X on reacting with iodine and water gives

AP EAPCET 2025 - 21st May Morning Shift
27

Identify the correct sets

(i) Boron fibres - bullet proof vest

(ii) Metal borides - protective shields

(iii) Borax - glass wool

Correct option is

AP EAPCET 2024 - 23th May Morning Shift
28
Hydrolysis of $\mathrm{XeF}_4$ gives $\mathrm{HF}, \mathrm{O}_2, \mathrm{Xe}$ and ' $X$ '. The structure of ' $X$ ' is
AP EAPCET 2024 - 23th May Morning Shift
29

Two statements are given below.

Statement I : $\mathrm{SnF}_4, \mathrm{PbF}_4$ are ionic in nature.

Statement II : GeCl ${ }_2$ is more stable than $\mathrm{GeCl}_4$

The correct answer is

AP EAPCET 2024 - 22th May Evening Shift
30

In which of the following sets allotropes of carbon are correctly matched with their uses?

i. Graphite - Crucibles

ii. Activated charcoal - Water filters

iii. Carbon black - Fuel

The correct answer is

AP EAPCET 2024 - 22th May Morning Shift
31
Two of the products formed by the reaction of ' $X$ with HCl are gases. What is ' $X$ '?
AP EAPCET 2024 - 22th May Morning Shift
32
Hydrated sodium aluminium silicate is called
AP EAPCET 2024 - 21th May Evening Shift
33
Which of the allotropic forms of carbon is aromatic in nature?
AP EAPCET 2024 - 21th May Evening Shift
34

$\mathrm{P}_2 \mathrm{O}_3+\mathrm{H}_2 \mathrm{O} \rightarrow X$, Red $\mathrm{P}_4+$ alkali $\rightarrow Y$

$X, Y$ are oxoacids of phosphorous. The number of $\mathrm{P}-\mathrm{OH}$ bonds in $X, Y$ respectively is

$$ \mathrm{P}_2 \mathrm{O}_3+\mathrm{H}_2 \mathrm{O} \rightarrow X $$

AP EAPCET 2024 - 21th May Evening Shift
35
A Lewis acid ' $X$ ' reacts with $\mathrm{LiAlH}_4$ in ether medium to give a highly toxic gas. ${ }^{\prime} Y^{\prime}$, ' $Y$ ' when heated with $\mathrm{NH}_3$ gives a compound known as inorganic benzene. ' $Y^{\prime}$ burns in oxygen and gives $\mathrm{H}_2 \mathrm{O}$ and ' $Z$ ', ' $Z$ ' is
AP EAPCET 2024 - 21th May Morning Shift
36

Which of the following are correct?

i. Basic structural unit of silicates is $-R_2 \mathrm{SiO}-$

ii. Silicones are biocompatible

iii. Producer gas contains CO and $\mathrm{N}_2$

The correct option is

AP EAPCET 2024 - 20th May Evening Shift
37
' $X$ ' on hydrolysis gives two products. One of them is solid. What is ' $X$ '?
AP EAPCET 2024 - 20th May Morning Shift
38

Which of the following reactions give phosphine?

i. Reaction of calcium phosphide with water

ii. Heating white phosphorous with concentrated NaOH solution in inert atmosphere

iii. Heating red phosphorous with alkali

AP EAPCET 2024 - 20th May Morning Shift
39

Observe the following stoichiometric equation

$$ \mathrm{P}_4+3 \mathrm{OH}^{-}+3 \mathrm{H}_2 \mathrm{O} \rightarrow \mathrm{PH}_3+3 x^{-} $$

What is the conjugate acid of $x^{-}$?

AP EAPCET 2024 - 19th May Evening Shift
40

Identify the correct statements

i. Oxidation of $\mathrm{NaBH}_4$ with $\mathrm{I}_2$ gives $\mathrm{B}_2 \mathrm{H}_6$

ii. $\mathrm{B}_2 \mathrm{H}_6$ burns in oxygen and releases an enormous amount of energy

iii. $\mathrm{B}_2 \mathrm{H}_6$ on hydrolysis gives a tribasic acid

AP EAPCET 2024 - 19th May Evening Shift
41
The disproportionation products of ortho phosphorus acid are
AP EAPCET 2024 - 19th May Evening Shift
42
Aluminium carbide on reaction with $\mathrm{D}_2 \mathrm{O}$ gives $\mathrm{Al}(O D)_3$ and ' $X^{\prime}$. What is ' $X^{\prime}$ '?
AP EAPCET 2024 - 18th May Morning Shift
43
When chlorine reacts with hot and conc. NaOH . The products formed are
AP EAPCET 2024 - 18th May Morning Shift
44

Identify the $$P$$ and $$Q$$ of the following reaction

$$P+Q \longrightarrow\left[B(O H)_4\right]^{-}+\mathrm{H}_3 \mathrm{O}^{+}$$

AP EAPCET 2022 - 5th July Morning Shift
45

Among $$\mathrm{P}_4, \mathrm{~S}_8$$ and $$\mathrm{N}_2$$ the elements which undergo disproportionation when heated with NaOH solution.

AP EAPCET 2022 - 4th July Evening Shift
46

Identify the correct statements about the anomalous behaviour of boron.

I. Boron trihalides can form dimeric structures.

II. Boron shows +1 as stable oxidation state.

III. Maximum covalency of boron is four.

IV. Boron does not form $$\mathrm{BF}_6^{6-}$$ ion.

AP EAPCET 2022 - 4th July Evening Shift
47

Which of the following is formed when $$\mathrm{SO}_3$$ is absorbed by concentrated $$\mathrm{H}_2 \mathrm{SO}_4$$ ?

AP EAPCET 2022 - 4th July Evening Shift
48

Identify the correct statements about boron.

I. It has high melting point.

II. It has high density.

III. It has high electrical conductivity.

IV. B-10 isotope of it has high ability to absorb neutrons.

AP EAPCET 2022 - 4th July Morning Shift
49

Assertion (A) HCl gas is dried by passing through concentrated H$$_2$$SO$$_4$$.

Reason (R) HCl gas reacts with NH$$_3$$ that gives white fumes.

AP EAPCET 2022 - 4th July Morning Shift
50

$$\mathrm{H}_3 \mathrm{BO}_3$$ or $$\mathrm{B}(\mathrm{OH})_3$$ is considered as an acid because its molecule

AP EAPCET 2021 - 20th August Evening Shift
51

Xenon best reacts with

AP EAPCET 2021 - 20th August Evening Shift
52

The correct order of acidic character of the following is

AP EAPCET 2021 - 20th August Evening Shift
53

In the following reactions (i) and (ii), the number of moles of chlorine gas released respectively are

(i) $$\mathrm{MnO}_2+4 \mathrm{HCl} \longrightarrow$$

(ii) $$\mathrm{KMnO}_4+16 \mathrm{HCl} \longrightarrow$$

AP EAPCET 2021 - 20th August Evening Shift
54

What would be the product of following reaction?

$$\mathrm{SiCl}_4 \stackrel{\text { Excess of } \mathrm{H}_2 \mathrm{O}}{\longrightarrow} \text { ? (Major product) }$$

AP EAPCET 2021 - 20th August Morning Shift
55

Identify (P) and (Q) in the following reaction.

AP EAPCET 2021 - 19th August Morning Shift Chemistry - p-Block Elements Question 56 English

AP EAPCET 2021 - 19th August Morning Shift
56

Match the following compounds with their corresponding physical properties.

Column I Column II
A. $$\mathrm{IBr}$$ 1. Orange solid
B. $$\mathrm{CIF}_3$$ 2. Yellow-green liquid
C. $$\mathrm{BrF}_3$$ 3. Black solid
D. $$\mathrm{ICl}_3$$ 4. Colourless gas

AP EAPCET 2021 - 19th August Morning Shift