d and f Block Elements · Chemistry · AP EAPCET

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MCQ (Single Correct Answer)

1

Identify the ion (hydrated in solution) which is not correctly matched with its spin only magnetic moment (in BM) given in brackets

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2

Which one of the following statements is not correct?

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3
The amphoteric oxide of vanadium ( V ) reacts with alkali and forms an oxo ion ' $X$ ' and with acid forms an oxo ion $Y$. The oxidation states of ' V ' in $X$ and $Y$ are respectively
AP EAPCET 2025 - 23rd May Morning Shift
4

How many of the following lanthanide elements exhibit +4 oxidation state?

Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy

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5

$$ \text { Match the following } $$

$$
\text { List-I (Aquated ion) }
$$
$$
\text { List-II (Colour) }
$$
(A) $\mathrm{Ni}^{2+}$ (I) Violet
(B) $\mathrm{Fe}^{3+}$ (II) Blue
(C) $\mathrm{Mn}^{3+}$ (III) Yellow
(D) $\mathrm{V}^{4+}$ (IV) Red
(V) Green

Correct answer is

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6

The ion with $4 f^7$ configuration is

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7

The correct order of oxidising power of the given ions is

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8
Which of the following lanthanoids have [Xe] $4 f^x 5 d^1 6 s^2$ configuration in their ground state. $$ (X=1-14) $$
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9
Match the following.
List I List II
A. Technicium I. Non-metal
B. Fluorine II. Transition metal
C. Tellurium III. Lanthanoid
D. Dysprosium IV. Metalloid
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10
The transition metal with highest melting point is
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11
Which transition metal does not form 'MO' type oxide? ( $M=$ transition metal)
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12

Identify the isoelectronic pair of ions from the following.

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13

Assertion (A) Transition metals and their complexes show catalytic activity.

Reason (R) The activation energy of a reaction is lowered by the catalyst.

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14

A purple coloured compound of manganese $$(X)$$ decomposes on heating to liberate oxygen and forms compounds of manganese $$Y$$ and $$Z$$. Compound $$Z$$ reacts with $$\mathrm{KOH}$$ in presence of potassium nitrate to give compound $$Y$$. Compounds $$X, Y$$ and $$Z$$ respectively are

AP EAPCET 2021 - 20th August Evening Shift
15

Match the following columns and choose the correct code.

Column I
(Property)
Column II
(Metal)
A. Element with highest second ionisation enthalpy $$(\Delta_i H_2)$$ 1. CO
B. Element with highest third ionisation enthalpy $$(\Delta_i H_3)$$ 2. Cr
C. M in [M(CO)$$_6$$] 3. Cu
D. Element with highest heat of atomisation $$(\Delta_a H)$$ 4. Zn
5. Ni

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16

Which of the following is not arranged in the correct sequence?

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17

Which among the following is coloured?

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18

The electronic configuration of $$\mathrm{Fe}^{3+}$$ is (atomic number of $$\mathrm{Fe}=26$$ )

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19

The magnetic moment of Fe$$^{2+}$$ is ........ BM.

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20

Which of the following statement is not correct?

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21

To which group of the periodic table does an element having electronic configuration [Ar] 3d$$^5$$ 4s$$^2$$ belong?

AP EAPCET 2021 - 19th August Morning Shift