Consider the following.

Statement-I In the extraction of Al by Hall-Heroult process, pure $\mathrm{Al}_2 \mathrm{O}_3$ mixed with $\mathrm{Na}_3 \mathrm{AlF}_6$ lowers its melting point and increases conductivity.

Statement-II Zirconium metal is purified by zone refining method.

Which of the following is used as froth stabilizer in froth floatation process?

In the extraction of iron from haematite, the impurity $(x)$ of the ore is removed in the form of ' $y$ ', what are $x$ and $y$ respectively?

$$ \text { Which of the following sets are correctly matched? } $$

$$ \begin{array}{cll} \hline & \text { Metal } & \text { Refining Process } \\ \hline \text { I. } & \mathrm{Hg} & \text { Distillation } \\ \hline \text { II. } & \mathrm{Cu} & \text { Poling } \\ \hline \text { III. } & \mathrm{B} & \text { Zone refining } \\ \hline \text { IV. } & \mathrm{Ti} & \text { Liquation } \\ \hline \end{array} $$