One mole of a gas occupying 3 L volume is expanded against a constant external pressure of 1 bar to a volume of 15 L . Calculate work done by the system

Calculate $\Delta \mathrm{T}_{\mathrm{f}}$ of aqueous 0.01 m formic acid if van't Hoff factor is 1.1

$$\left[\mathrm{K}_{\mathrm{f}}=1.86 \mathrm{~K} \mathrm{~Kg} \mathrm{~mol}^{-1}\right]$$

Which among the following is NOT allylic halide?

Calculate the void volume of simple cubic unit cell if the volume of unit cell is $5.5 \times 10^{-22} \mathrm{~cm}^3$.