1
AP EAPCET 2025 - 21st May Morning Shift
MCQ (Single Correct Answer)
+1
-0

Which of the following complexes exhibit geometrical isomerism?

I. $\left[\mathrm{Co}(\mathrm{en})\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}_2\right] \mathrm{Cl}$

II. $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right] \mathrm{Cl}$

III. $\left[\mathrm{Co}(\mathrm{en})_3, \mathrm{Cl}_3\right.$

IV. $\left[\mathrm{Co}(\mathrm{en})_2 \mathrm{Cl}_2\right] \mathrm{Br}$

A

I, II and III only

B

II, III and IV only

C

I, II and IV only

D

II and III only

2
AP EAPCET 2024 - 23th May Morning Shift
MCQ (Single Correct Answer)
+1
-0

Arrange the following in the increasing order of their magnetic moments

I. $\left[\mathrm{Mn}(\mathrm{CN})_6\right]^{3-}$

II. $\left[\mathrm{Mn} \mathrm{Cl}_6\right]^{3-}$

III. $\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{3-}$

IV. $\left[\mathrm{FeF}_6\right]^{3-}$

A
III $<$ I $<$ IV $<$ II
B
III $<$ IV $<$ II $<$ I
C
IV $<$ II $<$ I $<$ III
D
III $<$ I $<$ II $<$ IV
3
AP EAPCET 2024 - 22th May Evening Shift
MCQ (Single Correct Answer)
+1
-0
Which complex among the follwing is most paramagnetic?
A
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{2+}$
B
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}$
C
$\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$
D
$\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}$
4
AP EAPCET 2024 - 22th May Morning Shift
MCQ (Single Correct Answer)
+1
-0

Match the complexes in List-I with their hybridisation in list-II.

List-I
(Complex)
List-II
(Hybridisation)
I $$
\mathrm{Ni}(C O)_4
$$
A $$
s p^3 d^2
$$
II $$
\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}
$$
B $$
d^2 s p^3
$$
III $$
\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}
$$
C $$
d s p^2
$$
IV $$
\left[\mathrm{CoF}_6\right]^{3-}
$$
D $$
s p^3
$$
A
I-C, II-D, III-A, IV - B
B
I-D, II-C, III-A, IV - B
C
I-D, II-C, III-B, IV - A
D
I-C, II-D, III-B, IV - A

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