1
AP EAPCET 2024 - 22th May Morning Shift
MCQ (Single Correct Answer)
+1
-0

Isomerisation of gaseous cyclobutene to butadiene is first order reaction. At $T(\mathrm{~K})$. The rate constant of reaction is $33 \times 10^{-4} \mathrm{~s}^{-1}$. What is the time required (in min ) to complete $90 \%$ of this reaction at the temperature? $(\log 2=03)$

A
116.67
B
233.34
C
58.34
D
350.0
2
AP EAPCET 2024 - 21th May Evening Shift
MCQ (Single Correct Answer)
+1
-0
$A \rightarrow P$ is a zero order reaction. At 298 K the rate constant of the reaction is $1 \times 10^{-3} \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1}$. Initial concentration of ' $A$ ' is $0.1 \mathrm{~mol} \mathrm{~L}^{-1}$. What is the concentration of ' $A$ after 10 sec ?
A
$0.09 \mathrm{~mol} \mathrm{~L}^{-1}$
B
$0.099 \mathrm{~mol} \mathrm{~L}^{-1}$
C
$0.087 \mathrm{~mol} \mathrm{~L}^{-1}$
D
$0.011 \mathrm{~mol} \mathrm{~L}^{-1}$
3
AP EAPCET 2024 - 21th May Morning Shift
MCQ (Single Correct Answer)
+1
-0
The rate constant of a first order reaction is $3.46 \times 10^{-2} \mathrm{~s}^{-1}$ at 298 K . What is the rate constant of the reaction at 350 K if its activation energy is $50.1 \mathrm{~kJ} \mathrm{~mol}^{-1}$, $\left(R=8.314 \mathrm{JK}^{-1} \mathrm{~mol}^{-1}\right)(\log 2=0.3010)$
A
$0.592 \mathrm{~s}^{-1}$
B
$0.692 \mathrm{~s}^{-1}$
C
$0.792 \mathrm{~s}^{-1}$
D
$0.892 \mathrm{~s}^{-1}$
4
AP EAPCET 2024 - 20th May Evening Shift
MCQ (Single Correct Answer)
+1
-0
At 298 K the value of $-\frac{\Delta\left[\mathrm{Br}^{-}\right]}{\Delta t}$ for the reaction,

$5 \mathrm{Br}^{-}(a q)+\mathrm{BrO}_3^{-}(a q)+6 \mathrm{H}^{+}(a q) \longrightarrow 3 \mathrm{Br}_2(a q)+3 \mathrm{H}_2 \mathrm{O}(l)$ is $X$ $\mathrm{mol} \mathrm{L} \mathrm{min}^{-1}$. What is the rate (in $\mathrm{mol} \mathrm{L}^{-1} \mathrm{~min}^{-1}$ ) of this reaction?
A
$5 x$
B
$x$
C
$\frac{x}{5}$
D
$-\frac{x}{5}$
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