Le-Chatelier's principle is not applicable to

Using the data provided, find the value of equilibrium constant for the following reaction at $$298 \mathrm{~K}$$ and $$1 \mathrm{~atm}$$ pressure.

$$\begin{aligned} \mathrm{NO}(g)+\frac{1}{2} \mathrm{O}_2(g) \rightleftharpoons & \mathrm{NO}_2(g) \\ \Delta_f H \mathrm{Y}[\mathrm{NO}(g)] & =90.4 \mathrm{~kJ} \mathrm{~mol}^{-1} \\ \Delta_f H \mathrm{Y}\left[\mathrm{NO}_2(g)\right] & =32.48 \mathrm{~kJ} \mathrm{~mol}^{-1} \\ \Delta S Y a t ~298 \mathrm{~K} & =-70.8 \mathrm{~JK}^{-1} \mathrm{~mol}^{-1} \end{aligned}$$

$$[\operatorname{antilog}(0.50)=3162 \text { ] }$$

Standard entropies of $$X_2, Y_2$$ and $$X Y_3$$ are 60, 40 and $$50 \mathrm{JK}^{-1} \mathrm{~mol}^{-1}$$ respectively. At what temperature, the following reaction will be at equilibrium? [given: $$\Delta H \Upsilon=-30 \mathrm{~kJ}$$]

$$\frac{1}{2} X_2+\frac{3}{2} Y_2 \rightleftharpoons X Y_3$$

For the reaction $$\mathrm{SO}_2(g)+\frac{1}{2} \mathrm{O}_2(g) \rightleftharpoons \mathrm{SO}_3(g)$$, the percentage yield of product at different pressure is shown in the figure. Then, which among the following is true?