For $$\mathrm{C{r_2}O_7^{2 - } + 14{H^ + } + 6{e^ - }\buildrel {Yields} \over \longrightarrow 2C{r^{3 + }} + 7{H_2}O,{E^\Upsilon } = 1.33}$$ V at $$[C{r_2}O_7^{2 - }] = 4.5$$ millimole, $$[C{r^{3 + }}] = 1.5$$ millimole and $$E = 1.067$$ V, then calculate the pH of the solution.
Assertion (A) Sodium acetate on Kolbe’s electrolysis gives ethane.
Reason (R) Methyl free radical is formed at cathode.
When a current of 10 A is passes through molten AlCl$$_3$$ for 1.608 minutes. The mass of Al deposited will be
[Atomic mass of Al = 27 g]
The molar conductivities $$\left(\lambda_{\mathrm{m}}^{\Upsilon}\right)$$ at infinite dilution of $$\mathrm{KBr}, \mathrm{HBr}$$ and $$\mathrm{KNH}_2$$ are 120.5, 420.6 and $$90.48 \mathrm{~S} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$$ respectively. Find the value of $$\lambda_{\mathrm{m}}^\Upsilon$$ for $$\mathrm{NH}_3$$.