Which from following catalysts is used in the Haber's process for manufacture of ammonia?

In a first order reaction if concentartion of reactant drops from $0.8 \mathrm{~mol} \mathrm{~L}^{-1}$ to $0.4 \mathrm{~mol} \mathrm{~L}^{-1}$ in 15 minute. What is the time required to drop concentration from $0.1 \mathrm{~mol} \mathrm{~L}^{-1}$ to 0.025 mol $\mathrm{L}^{-1}$.

Calculate the quantity of electricity required to liberate 0.1 mole of chlorine gas during electrolysis of molten sodium chloride.

What is IUPAC name of $\left(\mathrm{CH}_3\right)_4 \mathrm{C}$ ?