The van't Hoff Factor (i) for a dilute aqueous solution of $\mathrm{Na}_2 \mathrm{SO}_4$ is

Glucose is added to 1 litre of water to such an extent that $\Delta T_f / K_f$ equals to $\frac{1}{1000}$ ．The weight of glucose added is

$P$ and $Q$ combines to form two compounds $\mathrm{PQ}_2$ and $\mathrm{PQ}_3$. If $1 \mathrm{~g} ~\mathrm{PQ}{ }_2$ is dissolved in 51 g benzene the depression of freezing point becomes $0 \cdot 8^{\circ} \mathrm{C}$. On the other hand if $1 \mathrm{~g} ~\mathrm{PQ}_3$ is dissolved in 51 g of benzene, the depression of freezing point becomes $0.625^{\circ} \mathrm{C}$. The atomic mass of P and Q are $\left(\mathrm{K}_{\mathrm{f}}\right.$ of benzene $=5 \cdot 1 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1})$

The correct order of boiling point of the given aqueous solutions is