MCQ (Single Correct Answer)

1

At 25$$^\circ$$C, the ionic product of water is 10$$^{-14}$$. The free energy change for the self-ionization of water in kCal mol$$^{-1}$$ is close to

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2

Equal volumes of aqueous solution of $$0.1(\mathrm{M}) \mathrm{HCl}$$ and $$0.2(\mathrm{M}) \mathrm{H}_2 \mathrm{SO}_4$$ are mixed. The concentration of $$\mathrm{H}^{+}$$ ions in the resulting solution is

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3

Correct solubility order of $$\mathrm{AgF}, \mathrm{AgCl}, \mathrm{AgBr}, \mathrm{AgI}$$ in water is

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4

What will be the change in acidity if

(i) $$\mathrm{CuSO}_4$$ is added in saturated $$(\mathrm{NH}_4)_2 \mathrm{SO}_4$$ solution

(ii) $$\mathrm{SbF}_5$$ is added in anhydrous $$\mathrm{HF}$$

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5

Number of moles of ions produced by complete dissociation of one mole of Mohr's salt in water is

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6

$$\mathrm{pH}$$ of $$10^{-8}(\mathrm{M}) \mathrm{~HCl}$$ solution is

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7

The specific conductance $$(\mathrm{k})$$ of $$0.02(\mathrm{M})$$ aqueous acetic acid solution at $$298 \mathrm{~K}$$ is $$1.65 \times 10^{-4} \mathrm{~S} \mathrm{~cm}^{-1}$$. The degree of dissociation of acetic acid is

$$[\lambda_{\mathrm{O}^{+}}+=349.1 \mathrm{~S} \mathrm{~cm}^2 \mathrm{~mol}^{-1} \text { and } \lambda_{{ }^{\circ} \mathrm{CH}_3 \mathrm{COO}^{-}}=40.9 \mathrm{~S} \mathrm{~cm}^2 \mathrm{~mol}^{-1}]$$

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8

At STP, the dissociation reaction of water is $$\mathrm{H_2O\rightleftharpoons H^+~(aq.)+OH^-~(aq.)}$$, and the pH of water is 7.0. The change of standard free energy ($$\Delta$$G$$^\circ$$) for the above dissociation process is given by

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9
Solubility products (Ksp) of the salts of types MX, MX2 and M3X at temperature T are 4.0 $$\times$$ 10$$-$$8, 3.2 $$\times$$ 10$$-$$14 and 2.7 $$\times$$ 10$$-$$15 respectively. Solubilities (in mol dm$$-$$3) of the salts at temperature T are in the order.
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10
A saturated solution of BaSO4 at 25$$^\circ$$C is 4 $$\times$$ 10$$-$$5 M. The solubility of BaSO4 in 0.1 M Na2SO4 at this temperature will be
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11
A solution is saturated with SrCO3 and SrF2. The $$[CO_3^{2 - }]$$ is found to be 1.2 $$ \times $$ 10-3 M. The concentration of F- in the solution would be

Given : Ksp(SrCO3) = 7.0 $$ \times $$ 10-10,

Ksp(SrF2) = 7.9 $$ \times $$ 10-10
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12
Which of the following mixtures will have the lowest pH at 298 K?
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13
Dissolving NaCN in de-ionised water will result in a solution having
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14
PbCl2 is insoluble in cold water. Addition of HCl increases its solubility due to
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15
Of the following compounds, which one of the strongest Bronsted acid in a aqueous solution?
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16
The molar solubility (in mol L$$-$$1) of a sparingly soluble salt MX4 is 'S'. The corresponding solubility product is Ksp. S in terms of 'Ksp' is given by the relation
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MCQ (More than One Correct Answer)

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